Organic Chemistry in Confining Media

Description

Zory Vlad Todres' monograph offers a fresh insight into an important and developed area of organic chemistry. Calixarene, cyclodextrins, and cucurbiturils as host molecules are well known, but the corresponding new and demonstrative publications deserve new exposition. This book principally widens our consideration of organic reactivity in confining media. Topics discussed include: effects of micellization, porous effects, effects of solvent cages, complexation to organometallic compounds, hydrogen-bond or charge-transfer complexation, sorption effects, effects of solvents, and stereochemical changes upon confinement. Organic Chemistry in Confining Media is useful for experienced organic chemists working in academia or industry, as well as chemists working in fields contiguous to organic chemistry. Front Matter....Pages i-xiii Encapsulation Effects....Pages 1-63 Resin-Docking, Polymer-Penetration, and Surface-Engrafting Effects....Pages 65-70 Reactions Within Charge-Transfer Complexes....Pages 71-87 Effects of Hydrogen Bonding....Pages 89-102 Effects of Coordination to Metals....Pages 103-113 Effects of Sorption....Pages 115-127 Micellar Effects....Pages 129-135 Cage Effects of Solvents, Proteins, and Crystal Lattices....Pages 137-141 Pore Effects....Pages 143-167 Stereochemical Outcomes of Confinement....Pages 169-177 The Role of Solvents in Confined Organic and Organometallic Reactions....Pages 179-187 Conclusions....Pages 189-190 Back Matter....Pages 191-194