Organophosphorus Chemistry: Volume 50

Description

This annual review of the literature, the 50th volume in the present series, provides a comprehensive and critical survey of a vast field of study involving organophosphorus compounds, ranging from phosphines, their chalcogenide derivatives and phosphonium salts, phosphorus (III) acid derivatives, phosphorus (V) acids, penta- and hexa-coordinated phosphorus compounds, phosphazenes and related phosphorus-nitrogen bonded compounds. Coverage is also presented of applications of organophosphorus compounds in homogeneous catalysis for synthesis of bulk and fine chemicals and also in applications as reagents in green synthetic procedures. Cover Preface Author biographies Contents Abbreviations Phosphines: preparation and reactivity 1 Reactions of elemental phosphorus 2 Organophosphorus catalysis 3 Phosphorus and frustrated Lewis pair chemistry References Tertiary phosphines: preparation and reactivity 1 Introduction 2 Preparation of phosphines 3 Reactivity of phosphines References Tervalent phosphorus acid derivatives 1 Introduction 2 Halophosphines 3 Tervalent phosphorus esters 4 Tervalent phosphorus amides 5 Mixed phosphorus (III) compounds compounds References Phosphine chalcogenides References Phosphonium salts and P-ylides 1 Introduction 2 Phosphonium salts 3 Phosphonium based ionic liquids (PILs) 4 P-Ylides (phosphoranes) References Homogeneous catalysis for bulk and fine chemicals. Adventures with phosphorus ligands 1 Introduction 2 The first steps. Using water-soluble bisphosphine ligands in asymmetric imine hydrogenation 3 Research for bulk chemicals. Use of bulky bidentate phosphites in isomerising hydroformylation 4 Asymmetric hydrogenation part 2. Monodentate phosphoramidites 5 Secondary phosphine oxides. A new class of stable (chiral) ligands Acknowledgements References Quinquevalent phosphorus acids 1 Introduction 2 Phosphoric acids and their derivatives 3 Phosphonic acids and their derivatives 4 Phosphinic acids and their derivatives 5 Quinquevalent phosphorus acids and their derivatives as catalysts Acknowledgements References Pentacoordinated and hexacoordinated compounds 1 Introduction 2 Pentacoordinated phosphorus compounds 3 Hexacoordinated phosphorus compounds References Phosphazenes a) Acyclic phosphazenes b) Cyclophosphazenes c) Polyphosphazenes References Green synthetic approaches in organophosphorus chemistry: recent developments 1 Introduction 2 Recent developments in green synthetic approaches in organophosphorus chemistry 3 Conclusions Acknowledgements References