ENGLISH

Quinoxalines: Synthesis, Reactions, Mechanisms and Structure

By Vakhid A. Mamedov

Book information

Publisher
Springer
Year
2016
ISBN
3319297716, 9783319297712
DOI
10.1007/978-3-319-29773-6
LCC
2016931837
Language
english
Format
PDF
Filesize
35 MB (37028469 bytes)
Pages
xvi+437\455
Topic
Chemistry Materials
Orientation
yes
Paginated
yes
Scanned
portrait
Time added
2016-05-19 17:20:35
Organic Chemistry; Medicinal Chemistry; Industrial

Description

This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on “Condensed Pyrazines” by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and  the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.

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