ENGLISH

Introduction to chemical engineering thermodynamics

By Hendrick C. Van Ness; Michael M. Abbott; Joseph Mauk Smith; Mark Thomas Swihart

Book information

Year
2022
ISBN
9781260721478, 1260721477, 9781260792751, 1260792757
Language
english
Format
PDF
Filesize
91 MB (95690355 bytes)
Edition
Nineth
Pages
\781
Time added
2022-03-29 18:49:05

Description

Cover Title Page Copyright Page Contents Preface List of Symbols 1 INTRODUCTION 1.1 The Scope of Thermodynamics 1.2 International System of Units 1.3 Measures of Amount or Size 1.4 Temperature 1.5 Pressure 1.6 Work 1.7 Energy 1.8 Heat 1.9 Synopsis 1.10 Problems 2 THE FIRST LAW AND OTHER BASIC CONCEPTS 2.1 Joule’s Experiments 2.2 Internal Energy 2.3 The First Law of Thermodynamics 2.4 Energy Balance for Closed Systems 2.5 Equilibrium and the Thermodynamic State 2.6 The Reversible Process 2.7 Closed-System Reversible Processes; Enthalpy 2.8 Heat Capacity 2.9 Mass and Energy Balances for Open Systems 2.10 Synopsis 2.11 Problems 3 VOLUMETRIC PROPERTIES OF PURE FLUIDS 3.1 The Phase Rule 3.2 PVT Behavior of Pure Substances 3.3 Ideal Gas and Ideal-Gas State 3.4 Virial Equations of State 3.5 Application of the Virial Equations 3.6 Cubic Equations of State 3.7 Generalized Correlations for Gases 3.8 Generalized Correlations for Liquids 3.9 Synopsis 3.10 Problems 4 HEAT EFFECTS 4.1 Sensible Heat Effects 4.2 Latent Heats of Pure Substances 4.3 Standard Heat of Reaction 4.4 Standard Heat of Formation 4.5 Standard Heat of Combustion 4.6 Temperature Dependence of ΔH° 4.7 Heat Effects of Industrial Reactions 4.8 Synopsis 4.9 Problems 5 THE SECOND LAW OF THERMODYNAMICS 5.1 Axiomatic Statements of the Second Law 5.2 Heat Engines and Heat Pumps 5.3 Carnot Engine with Ideal-Gas-State Working Fluid 5.4 Entropy 5.5 Entropy Changes for the Ideal-Gas State 5.6 Entropy Balance for Open Systems 5.7 Calculation of Ideal Work 5.8 Lost Work 5.9 The Third Law of Thermodynamics 5.10 Entropy from the Microscopic Viewpoint 5.11 Synopsis 5.12 Problems 6 THERMODYNAMIC PROPERTIES OF FLUIDS 6.1 Fundamental Property Relations 6.2 Residual Properties 6.3 Residual Properties from the Virial Equations of State 6.4 Generalized Property Correlations for Gases 6.5 Two-Phase Systems 6.6 Thermodynamic Diagrams 6.7 Tables of Thermodynamic Properties 6.8 Synopsis 6.9 Addendum. Residual Properties in the Zero-Pressure Limit 6.10 Problems 7. APPLICATIONS OF THERMODYNAMICS TO FLOW PROCESSES 7.1 Duct Flow of Compressible Fluids 7.2 Turbines (Expanders) 7.3 Compression Processes 7.4 Synopsis 7.5 Problems 8 PRODUCTION OF POWER FROM HEAT 8.1 The Steam Power Plant 8.2 Internal-Combustion Engines 8.3 Jet Engines; Rocket Engines 8.4 Synopsis 8.5 Problems 9 REFRIGERATION AND LIQUEFACTION 9.1 The Carnot Refrigerator 9.2 The Vapor-Compression Cycle 9.3 The Choice of Refrigerant 9.4 Absorption Refrigeration 9.5 The Heat Pump 9.6 Liquefaction Processes 9.7 Synopsis 9.8 Problems 10 THE FRAMEWORK OF SOLUTION THERMODYNAMICS 10.1 Fundamental Property Relation 10.2 The Chemical Potential and Equilibrium 10.3 Partial Properties 10.4 The Ideal-Gas-State Mixture Model 10.5 Fugacity and Fugacity Coefficient: Pure Species 10.6 Fugacity and Fugacity Coefficient: Species in Solution 10.7 Generalized Correlations for the Fugacity Coefficient 10.8 The Ideal-Solution Model 10.9 Excess Properties 10.10 Synopsis 10.11 Problems 11 MIXING PROCESSES 11.1 Property Changes of Mixing 11.2 Heat Effects of Mixing Processes 11.3 Synopsis 11.4 Problems 12 PHASE EQUILIBRIUM: INTRODUCTION 12.1 The Nature of Equilibrium 12.2 The Phase Rule and Duhem’s Theorem 12.3 Vapor/Liquid Equilibrium: Qualitative Behavior 12.4 Equilibrium and Phase Stability 12.5 Vapor/Liquid/Liquid Equilibrium 12.6 Synopsis 12.7 Problems 13 THERMODYNAMIC FORMULATIONS FOR VAPOR/LIQUID EQUILIBRIUM 13.1 Excess Gibbs Energy and Activity Coefficients 13.2 The Gamma/Phi Formulation of VLE 13.3 Simplifications: Raoult’s Law, Modified Raoult’s Law, and Henry’s Law 13.4 Correlations for Liquid-Phase Activity Coefficients 13.5 Fitting Activity Coefficient Models to VLE Data 13.6 Residual Properties by Cubic Equations of State 13.7 VLE from Cubic Equations of State 13.8 Flash Calculations 13.9 Synopsis 13.10 Problems 14 CHEMICAL-REACTION EQUILIBRIA 14.1 The Reaction Coordinate 14.2 Application of Equilibrium Criteria to Chemical Reactions 14.3 The Standard Gibbs-Energy Change and the Equilibrium Constant 14.4 Effect of Temperature on the Equilibrium Constant 14.5 Evaluation of Equilibrium Constants 14.6 Relation of Equilibrium Constants to Composition 14.7 Equilibrium Conversions for Single Reactions 14.8 Phase Rule and Duhem’s Theorem for Reacting Systems 14.9 Multireaction Equilibria 14.10 Fuel Cells 14.11 Synopsis 14.12 Problems 15 TOPICS IN PHASE EQUILIBRIA 15.1 Liquid/Liquid Equilibrium 15.2 Vapor/Liquid/Liquid Equilibrium (VLLE) 15.3 Solid/Liquid Equilibrium (SLE) 15.4 Solid/Vapor Equilibrium (SVE) 15.5 Equilibrium Adsorption of Gases on Solids 15.6 Osmotic Equilibrium and Osmotic Pressure 15.7 Synopsis 15.8 Problems 16 THERMODYNAMIC ANALYSIS OF PROCESSES 16.1 Thermodynamic Analysis of Steady-State Flow Processes 16.2 Synopsis 16.3 Problems A Conversion Factors and Values of the Gas Constant B Properties of Pure Species C Heat Capacities and Property Changes of Formation D The Lee/Kesler Generalized-Correlation Tables E Steam Tables F Thermodynamic Diagrams G UNIFAC Method H Newton’s Method Index

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