Nanooptics and Photonics, Nanochemistry and Nanobiotechnology, and Their Applications: Selected Proceedings of the IX International Conference Nanotechnology and Nanomaterials (NANO2021), 25–28 August 2021, Lviv, Ukraine

Description

This book highlights some of the latest advances in nanotechnology and nanomaterials from leading researchers in Ukraine, Europe and beyond. It features contributions presented at the 9th International Science and Practice Conference Nanotechnology and Nanomaterials (NANO2021), which was held on August 25–28, 2021 at Lviv Polytechnic National University, and was jointly organized by the Institute of Physics, the National Academy of Sciences of Ukraine, Lviv Polytechnic National University, University of Tartu (Estonia), University of Turin (Italy), Pierre and Marie Curie University (France), European Profiles S.A. (Greece), Representation of the Polish Academy of Sciences in Kyiv, University of Angers (France), Ruprecht Karl University of Heidelberg (Germany). Internationally recognized experts from a wide range of universities and research institutions share their knowledge and key findings on material properties, behavior, and synthesis. This book’s companion volume also addresses topics such as nano-optics, energy storage, and biomedical applications. Preface Contents Contributors Part I Nanochemistry and Biotechnology 1 The Effect of Medium Acidity and Basicity on the Stability of Tryptophan and Formylkynurenine Species with Silver 1.1 Introduction 1.2 Experimental and Theoretical Methods 1.2.1 Silver Colloids 1.2.2 Investigation Methods 1.2.3 Details of Calculations 1.3 Results and Discussion 1.4 Conclusion References 2 Dielectric Properties of Blood Cells as Biomarkers for Stroke Diagnostics 2.1 Introduction 2.2 Microwave Dielectrometry Technique in Complex Study of Microparticles 2.3 Materials and Method 2.4 Mathematical Modeling of RBC Dielectric Properties 2.5 Results and Discussion 2.5.1 Temperature Effects 2.5.2 Time of Dielectric Relaxation Study 2.6 Conclusions References 3 Catalysis of Wastewater Pollutants by Ruthenium Nanooxide in Porous Glass 3.1 Introduction 3.2 The Formulation of the Problem 3.3 The Choice of Matrix 3.4 Luminescent Studies 3.5 Conclusion References 4 Physical, Nanostructural, and Biocolloid-Chemical Transformations of Marine Iron-Aluminosilicate Sediments and Their Chemical, and Mineral Ore Conversions 4.1 Introduction 4.2 Materials and Methods 4.3 Results and Discussion 4.3.1 Current Status of Iron-Aluminosilicate System (IASs) Studies 4.3.2 Analysis of Experimental Data Using Theoretical and Model Conceptions 4.4 Conclusions References 5 Prospects for the Catalytic Conversion of Plastic Waste 5.1 Existing Approaches to Plastic Disposal 5.2 Prospects for Catalytic Thermochemical Conversion in the Recycling of Plastics 5.3 From Traditional Catalysts to Biocatalysts in Plastic Recycling 5.4 Conclusions References 6 Antibiotic-Loaded Polyacrylamide-Based Hydrogels for Infected Wound Care 6.1 Introduction 6.2 Experimental 6.2.1 Reagents 6.2.2 Syntheses of Hydrogels 6.2.3 Preparation of Antibiotic-Loaded Hydrogels 6.2.4 Antibiotic Release Study 6.2.5 Antibacterial Activity Testing 6.3 Results and Discussion 6.4 Conclusions References 7 Prediction of Isomorphous Substitutions and Stability of Solid Solutions with β-YF3 Structure in Lu1–xLnxF3, Ln = Sm–Yb Systems 7.1 Prospects for the Practical Use of Solid Solutions of Lu1–xLnxF3, Ln = Sm–Yb, with β-YF3 Structure 7.2 Calculation Procedure and Initial Data 7.3 Calculation Results for Lu1–xLnxF3 (Ln = Sm–Yb) Solid Solutions with β-YF3 Structure 7.4 Comparison of the Results Obtained with the Literature Data 7.5 Conclusions References 8 Viability of Deconserved Sheep Sperm for Adding Nanomaterial of Ultrafine Silica 8.1 Introduction 8.2 Materials and Methods of Study 8.3 Results and Discussion 8.4 Conclusions References 9 The Effect of Stirring on the Electrodeposition of [(Cu–Zn)base/(Cu–Zn)add]n Coatings from Pyrophosphate-Citrate Electrolyte 9.1 Introduction 9.2 Experimental 9.3 Experimental Results and Discussion 9.4 Conclusions References 10 Features of Plasma-Electrolyte Synthesis of Heterooxide Nanocomposites on Multicomponent Alloys of Valve Metals 10.1 Experimental 10.1.1 The Materials, Electrolytes, and Modes 10.1.2 The Research Methods 10.2 Surface Homogenization of Valve Metals 10.2.1 Surface Homogenization of Aluminum Alloys 10.2.2 Features of Surface Homogenization of Titanium Alloys 10.2.3 Rationalization of Electrolyte Composition and Modes for Surface Homogenization of Multicomponent Alloys 10.3 Formation of Heterooxide Nanocomposites on Multicomponent Aluminum and Titanium Alloys 10.4 Conclusions References 11 Deterioration of Crack Growth Resistance Characteristics of a Fine-Grained YSZ–NiO(Ni) Anode Material During Its Degradation in a Hydrogen Sulfide Containing Atmosphere 11.1 Introduction 11.2 Materials and Methods 11.3 Results and Discussion 11.4 Conclusions References 12 Synthesis and Characterization of Deca-Quinoline Bearing Pillar[5]arene Macrocycle 12.1 Introduction 12.2 Experiment Details 12.2.1 The Synthesis of 1,4-bis(3-bromopropoxy)benzene (Compound 3) 12.2.2 The Synthesis of deca(3-bromopropane) Pillar[5]arene (Compound 4) 12.2.3 The Synthesis of deca(3-azidopropane) Pillar[5]arene (Compound 5) 12.2.4 The Synthesis of N-(prop-2-yn-1-yl)quinolin-8-amine (Compound 8) 12.2.5 The Synthesis of Q-Pillar[5]arene 12.3 Results and Discussion 12.4 Conclusions References 13 Synthesis and Photochemical Properties of Benzylidene-Containing Polymers 13.1 Introduction 13.2 Experimental 13.2.1 Methods 13.2.2 Materials 13.3 Results and Discussion 13.4 Conclusion References 14 POSS-Containing Nanocomposites Based on Polyurethane/Poly(Hydroxypropyl Methacrylate) Semi-IPN Matrix 14.1 Introduction 14.2 Materials and Testing Methods 14.2.1 Materials 14.2.2 Testing Methods 14.3 Results and Discussion 14.3.1 Fourier Transform Infrared Spectroscopy (FTIR) 14.3.2 Thermodynamics of Polymer-Filler Interactions in the Nanocomposites 14.3.3 Thermal Properties of the Nanocomposites 14.3.4 Porosity of Native Matrix and Nanocomposites 14.3.5 Morphology of Native Matrix and Nanocomposites 14.4 Conclusion References 15 Iron Oxide Nanomaterials for Bacterial Inactivation and Biomedical Applications 15.1 Introduction 15.2 Bacterial Inactivation with Iron Oxides 15.2.1 The Effect of the Synthesis Method on the Antibacterial Properties of Iron Oxides 15.2.2 Iron Oxides and Their Bacterial Inactivation Mechanism 15.3 Iron Oxides as Drug Carriers 15.3.1 The Use of Iron Oxides in Medicine 15.3.2 The Use of Magnetic Materials for Drug Delivery 15.4 Conclusions References 16 Proliferative Activity of Ehrlich Carcinoma Cells After Use of Nanocomplexes 16.1 Introduction 16.2 Synthesis of Nanocomplexes 16.3 Proliferative Activity of Ehrlich Ascites Carcinoma Cells After Use of Nanocomplexes 16.4 Conclusions References 17 Extraction and Properties of Nanocellulose from Hemp Fibers 17.1 Introduction 17.2 Experiment 17.2.1 Materials 17.2.2 Methods 17.3 Results and Discussion 17.3.1 Chemical Composition 17.3.2 Morphology 17.3.3 Mathematical Modeling 17.3.4 Nanosize 17.4 Conclusion References 18 Impact of Gold Nanoparticles on Metabolic and Antioxidant Status of Cryopreserved Mesenchymal Stem Cells from Adipose Tissue 18.1 Introduction 18.2 Materials and Methods 18.3 Results and Discussion 18.4 Conclusion References 19 Chemical Transformations of Phosphoric Acid on Hydrated Anatase Surface: A Quantum Chemical Simulation 19.1 Introduction 19.2 Research Methods and Objects 19.3 Results and Discussion 19.4 Conclusions References 20 Structural Functionalization of the Polymer Matrix in PVC-MWCNT Nanocomposites 20.1 Introduction 20.2 Experimental Studies 20.3 Results and Discussion 20.4 Conclusion References 21 Hydrogel Materials for Biomedical Application: A Review 21.1 Introduction 21.2 Synthesis and Characteristic of Chemically Cross-Linked Hydrogels Dextran-Polyacrylamide 21.2.1 Synthesis of Chemically Cross-Linked Hydrogels 21.2.2 FTIR Spectroscopy 21.2.3 Morphological Characterization 21.2.4 Swelling 21.2.5 Sorption Properties 21.3 Hydrogels as Matrices for the Synthesis and Stabilization of Nanoparticles 21.4 Hydrogels as Materials for Wound Dressings 21.4.1 Antibacterial Wound Dressings with Silver Nanoparticles 21.4.2 Comparison of Antibacterial Efficacy of Composites Hydrogel/AgNPs and Hydrogels/Chlorohexidine 21.4.3 Testing of Hydrogel Composites with AgNPs on Open Wounds 21.4.4 Testing of Hydrogel Composites with AgNPs on Open Human Wounds 21.4.5 Hydrogel Materials for Photodynamic Therapy of Open Wounds 21.4.6 Hydrogel Materials for Drug Delivery 21.5 Conclusion References Part II Nanooptics and Photonics 22 Properties of Renormalized Spectra of Localized Quasiparticles Interacting with One- and Two-Mode Phonons in Davydov’s Model at T = 0K 22.1 Introduction 22.2 Electromagnetic Field Absorption Coefficient and Fourier Image of Retarded Green's Function 22.3 Properties of I(Α,ξ) Function for the One-Mode System 22.4 Properties of I(α1,α2,ξ) Form-Function for the Two-Mode System 22.5 Main Results and Conclusions References 23 Fluorinated Oligoazomethine with Azo Groups in the Main Chain as Stimuli-Responsive Photoactive Materials 23.1 Introduction 23.2 Experimental Section 23.2.1 Materials 23.2.2 Synthesis of Azo-Oam-1 23.2.3 Synthesis of Model Compound 3 (4,4'-((((perfluoro-1,4-phenylene)bis(oxy))bis(3,1-phenylene))bis(diazene-2,1-diyl))bis(2-(((2-hydroxyphenyl)imino)methyl)phenol)) 23.2.4 Characterization 23.3 Results and Discussion 23.3.1 Synthesis and General Properties of Azo-Oam-1 Oligomer 23.3.2 Optical Properties of Oligomer 23.3.3 Light-Induced Birefringence and Diffraction Gratings in the Azo-Oam-1 Film 23.4 Conclusion References 24 Surface Plasmon Enhanced Copper Monosulfide-Based Core–Shell Nanoparticles 24.1 Introduction 24.2 Background 24.3 Optical Properties of the Core–shell Nanostructures Under Localized Plasmon Resonance Condition 24.4 Conclusions References 25 Luminescent Properties of Opal–Active Dielectric Matrix Nanocomposites Activated by Ions of Rare-Earth Elements 25.1 Introduction and Background 25.2 Sample Preparation and Experimental Techniques 25.2.1 Synthetic Opals and Nanocomposite Based on Them 25.2.2 X-ray Diffraction Patterns of Nanocomposites 25.2.3 Measurement of Luminescence Spectra 25.3 Luminescence Spectra 25.3.1 Luminescence of Initial Active Dielectric Crystals 25.3.2 Luminescence of the Starting Compounds of Rare-Earth Elements 25.3.3 Luminescence of Rare-Earth Elements in the Pores of the Opal Matrix 25.3.4 Luminescence of Rare-Earth Elements in the Pores of Nanocomposites 25.4 Conclusions References 26 Nanostructured Optical Composites of TiO2(C3N4Ox)/PANI for Photocatalytic Application 26.1 Actuality 26.2 Introduction 26.3 Experimental Part 26.4 Synthesis of TiO2 Nanoparticles and Polyaniline 26.5 Modifications of TiO2 Followed by Polymerization with Layer Polyaniline 26.6 Synthesis of Doped O-C3N4 26.7 Results and Discussion 26.8 XPS_SEM 26.9 XRD 26.10 TEM and SEM 26.11 Optical Properties Study 26.12 Summary References 27 Local Modes and Local Resonances in Defect Containing 1D Photonic Structures: Signal Processing and Collimation of THz Irradiation 27.1 Introduction 27.2 Transmission Spikes of a Double Central Defect Containing 1D Resonator: Signal Processing Schemes 27.3 Energy Concentration and Collimation Effect in a Resonator Structure with Unitary Central Defect 27.4 Resonant Transmission-Based Filtering References 28 Features of Surface Structuring of Direct and Indirect Band Gap Semiconductors by Femtosecond Laser 28.1 Introduction 28.2 Experimental Details 28.3 Peculiarities of Femtosecond Light-Semiconductor Interaction in the Case of Direct Band Gap Semiconductors 28.4 Femtosecond Laser Processing of the Semiconductors with the Transition of Band Gap from a Direct Type to an Indirect Type 28.5 The Femtosecond Laser Processing of Indirect Band Gap Semiconductors 28.6 Conclusions References 29 Dielectric and Photoluminescent Properties of the Water–Cellulose–NaCl Systems in a Wide Range of Temperatures: What is the Role of Ions? 29.1 Introduction 29.2 Experiment 29.2.1 Composites 29.2.2 Methods 29.3 Results and Discussion 29.3.1 Dielectric Properties 29.3.2 Transmission Spectra 29.3.3 Luminescence Spectra 29.4 Discussion 29.5 Conclusions References