Metal-Catalyzed Reactions in Water
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Water is abundant in nature, non-toxic, non-flammable and renewable and could therefore be safer and economical for the chemical industry wherever it is used as a solvent. This book provides a comprehensive overview of developments in the use of water as a solvent for metal catalysis, illustrating the enormous potential of water in developing new catalytic transformations for fi ne chemicals and molecular materials synthesis. A group of international experts cover the most important metalcatalyzed reactions in water and bring together cutting-edge results from recent literature with the first-hand knowledge gained by the chapter authors. This is a must-have book for scientists in academia and industry involved in the field of catalysis, greener organic synthetic methods, water soluble ligands and catalyst design, as well as for teachers and students interested in innovative and sustainable chemistry. Content: Chapter 1 Metal?Catalyzed Cross?Couplings of Aryl Halides to Form C–C Bonds in Aqueous Media (pages 1–46): Kevin H. ShaughnessyChapter 2 Metal?Catalyzed C–H Bond Activation and C–C Bond Formation in Water (pages 47–86): Bin Li and Prof. Dr. Pierre H. DixneufChapter 3 Catalytic Nucleophilic Additions of Alkynes in Water (pages 87–108): Xiaoquan Yao and Chao?Jun LiChapter 4 Water?Soluble Hydroformylation Catalysis (pages 109–137): Duc Hanh Nguyen, Martine Urrutigoity and Philippe KalckChapter 5 Green Catalytic Oxidations in Water (pages 139–172): Roger A. SheldonChapter 6 Hydrogenation and Transfer Hydrogenation in Water (pages 173–242): Xiaofeng Wu and Jianliang XiaoChapter 7 Catalytic Rearrangements and Allylation Reactions in Water (pages 243–289): Victorio Cadierno, Joaquin Garcia?Alvarez and Sergio E. Garcia?GarridoChapter 8 Alkene Metathesis in Water (pages 291–336): Karol Grela, Lukasz Gulajski and Krzysztof SkowerskiChapter 9 Nanocatalysis in Water (pages 337–394): R. B. Nasir Baig and Rajender S. Varma
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