Active Metals: Preparation, Characterization, Applications
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Description
Reactions with metals are ubiquitous in organic synthesis and, particularly in the last few years, a large repertoire of methods for the activation of metals and for their use in organic synthesis has been developed. In Active Metals, topics ranging from morphology of metal clusters and nanometallurgy to organometallic chemistry, catalysis and the use of activated metals in natural product synthesis are authoritatively discussed by leading experts in the field. Active Metals will allow you to fully benefit from the recent advances in the field by giving: * Detailed experimental procedures * Guidance on manipulation of active metals under inert atmosphere * Valuable information for planning syntheses * Extensive tables of typical conversions with yields * Critically selected, up-to-date references This handbook is a unique source of 'hands-on' information which will allow you to expand the scope of your research. Content: Chapter 1 Rieke Metals: Highly Reactive Metal Powders Prepared by Alkali Metal Reduction of Metal Salts (pages 1–59): Reuben D. Rieke, Matthew S. Sell, Walter R. Klein, Tian?An Chen, Jeffrey D. Brown and Mark V. HansonChapter 2 Allylic Barium Reagents (pages 61–84): Akira Yanagisawa and Hisashi YamamotoChapter 3 The McMurry Reaction (pages 85–131): Thomas LectkaChapter 4 Ultrasound?Induced Activation of Metals: Principles and Applications in Organic Synthesis (pages 133–190): Jean?Louis Luche and Pedro CintasChapter 5 Preparation and Applications of Functionalized Organozinc Reagents (pages 191–236): Paul KnochelChapter 6 Metal Atom/Vapor Approaches to Active Metal Clusters/Particles (pages 237–278): Kenneth J. Klabunde and Galo Cardenas?TrivinoChapter 7 Electrochemical Methods in the Synthesis of Nanostructured Transition Metal Clusters (pages 279–297): Manfred T. Reetz, Wolfgang Helbig and Stefan A. QuaiserChapter 8 The Magnesium Route to Active Metals and Intermetallics (pages 299–338): L. E. Aleandri and B. BogdanovicChapter 9 Catalytically Active Metal Powders and Colloids (pages 339–379): Helmut Bonnemann and Werner BrijouxChapter 10 Supported Metals (pages 380–426): Alois FurstnerChapter 11 Morphological Considerations on Metal?Graphite Combinations (pages 427–446): Ferdinand Hofer
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