ENGLISH

Macromolecular Metal Carboxylates and Their Nanocomposites

By A. D. Pomogailo , G. I. Dzhardimalieva , V. N. Kestelman (auth.)

Book information

Publisher
Springer-Verlag Berlin Heidelberg
Year
2010
ISBN
3642105734, 9783642105739, 9783642105746
DOI
10.1007/978-3-642-10574-6
Language
english
Format
PDF
Filesize
6 MB (6431392 bytes)
Series
Springer Series in Materials Science 138
Edition
1
Pages
306\316
Time added
2011-06-04 13:46:07
generalMetallic Materials; Nanotechnology; Engineering

Description

Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are considered.

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