Alloy phase equilibria

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Amsterdam-London-New York: Elservier Publ. Comp., 1966. — 290 p.ContentsTribute to A. Prince by T. Chart and B. LegendrePrefaceAcknowledgements.Introductory thermodynamics .EquilibriumInternal energyHeat content or enthalpyEntropyFree energyThermodynamics of solutions SolutionsHeterogenous equilibrium-the phase ruleFree energy of solutionsThe free energy of phase mixturesVariation of solubility with temperatureBinary phase diagramsTwo-phase equilibriumIntroductionTwo phase equilibrium. Complete solubility of thecomponents in both the liquid and the solid state .Binary phase diagramsThree-phase equilibrium involving limited solubility of the components in the solid state but complete solubility in the liquid stateStructural factorsThree-phase equilibrium-eutectic reactionsThree-phase equilibrium-peritectic reactionsCongruent transformationsBinary phase diagramsLimited solubility in both the liquid and solid stateIntroductory thermodynamicsMonotectic reactionsSyntectic reactionsBinary phase diagramsReactions in the solid stateSolid state reactionsEutectoïd reactionsMonotectoïd reactionsPeritectoïd reactionsBinary phase diagramsAllotropy of the componentsSystems in which one phase is in equilibrium with the liquid phaseSystems in which two phases are in equilibrium with the liquid phaseTernary phase diagramsTwo-phase equilibriumIntroductionRepresentation of ternary systemsTie lines and tie trianglesTwo-phase equilibrium. Complete solubility of the components in both the liquid and the solid stateTernary phase diagramsThree-phase equilibriumProperties of three-phase tie trianglesThree-phase equilibrium produced by the coalescence of miscibility gapsThree-phase equilibrium involving eutectic reactionsThree-phase equilibrium involving peritectic reactionsTernary phase diagramsFour-phase equilibriumThe eutectic equilibrium l = α+β+γVariants of the ternary eutectic diagramThe quasi-peritectic equilibrium l+α = β+γT he ternary peritectic equilibrium l+α + β = γTernary phase diagramsIntermediate phases Congruently-melting intermediate phasesIncongruently-melting intermediate phasesTernary phase diagramsLiquid immiscibiltyTwo binary systems are monotecticOne binary system is monotecticNone of the binaries contain liquid miscibility gaps buttrue ternary liquid immiscibility appears .Ternary phase diagramsFour-phase equilibrium involving allotropy of one componentThe association of phase regions .Law of adjoining phase regionsDegenerate phase regionsTwo-dimensional sections of phase diagramsThe cross ruleNon-regular two-dimensional sectionsCritical pointsAssociation of phase regions in multi-components systemsQuaternary phase diagrams .Representation of quaternary systemsTwo-phase equilibriumThree-phase equilibriumFour-phase equilibriumFive-phase equilibriumTwo-dimensional polythermal sectionsComplex quaternary systemsAppendix Selected bibliography Index