ENGLISH

Chiral Diazaligands for Asymmetric Synthesis

By Marc Lemaire , Diego Savoia (auth.) , Pierre Mangeney (eds.)

Book information

Publisher
Springer-Verlag Berlin Heidelberg
Year
2005
ISBN
9783540260646, 3540260641
DOI
10.1007/b105252
Open Library ID
OL9055599M
Language
english
Format
PDF
Filesize
6 MB (6623596 bytes)
Series
Topics in Organometallic Chemistry 15
Edition
1
Pages
302\311
Library
kolxoz-dop
Time added
2010-02-18 13:16:04
Organometallic Chemistry; Medicinal Chemistry; Ino

Description

The use of phosphine derivatives has historically induced the tremendous development of catalysis (both non-asymmetric and asymmetric). Although the chemistry of amines is more documented, the use of nitrogen-containing ligands only appeared recently. Nevertheless, during the last ten years, the results describing chiral diamine preparations and their uses in asymmetric catalysis and synthesis are increasing faster than their phosphorus counterparts. The reader will find in this volume the most recent methods for the synthesis of chiral diamines as well as their applications in asymmetric catalysis of CC bond formation. Particular attention will be given to spartein and derivatives of such diamines. Recently, the particular properties and the chemistry of amines allowed to obtain catalysts easy to separate and recycle and new types of ligands such as diaminocarbenes, ureas and thioureas. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications.

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