Basic Principles and Calculations in Chemical Engineering

Description

About This eBook Halftitle Page Title Page Copyright Page Dedication Pearson’s Commitment to Diversity, Equity, and Inclusion Contents Preface How to Use this Book Learning Aids Good Learning Practices (Learning How to Learn) Suggestions to Enhance Learning Suggestions for How to Use This Book Effectively Acknowledgments About the Authors Part I: Introduction Chapter 1. Introduction to Chemical Engineering Introduction 1.1 A Brief History of Chemical Engineering 1.2 Types of Jobs Chemical Engineers Perform 1.3 Industries in Which Chemical Engineers Work 1.4 Sustainability Self-Assessment Test 1.5 Ethics Self-Assessment Test Summary Glossary Chapter 2. Introductory Concepts 2.1 Units of Measure Self-Assessment Test 2.2 Unit Conversions Self-Assessment Test 2.3 Equations and Units Self-Assessment Test 2.4 Measurement Errors and Significant Figures Self-Assessment Test 2.5 Validation of Results Self-Assessment Test 2.6 Mass, Moles, and Density Self-Assessment Test Self-Assessment Test Self-Assessment Test 2.7 Process Variables Self-Assessment Test Self-Assessment Test Self-Assessment Test Glossary Problems Part II: Material Balances Chapter 3. Material Balances Introductory Example 3.1 The Connection between a Process and Its Schematic Self-Assessment Test 3.2 Introduction to Material Balances Self-Assessment Test 3.3 A General Strategy for Solving Material Balance Problems Self-Assessment Test 3.4 Material Balances for Single Unit Systems Frequently Asked Questions Self-Assessment Test 3.5 Vectors and Matrices Self-Assessment Test 3.6 Solving Systems of Linear Equations with MATLAB Self-Assessment Test 3.7 Solving Systems of Linear Equations with Python Self-Assessment Test Summary Glossary Problems Chapter 4. Material Balances with Chemical Reaction Introduction 4.1 Stoichiometry Self-Assessment Test 4.2 Terminology for Reaction Systems Self-Assessment Test 4.3 Species Mole Balances Self-Assessment Test 4.4 Element Material Balances Self-Assessment Test 4.5 Material Balances for Combustion Systems Self-Assessment Test Summary Glossary Problems Chapter 5. Material Balances for Multiunit Processes Introduction 5.1 Preliminary Concepts 5.2 Sequential Multiunit Systems Self-Assessment Test 5.3 Recycle Systems Self-Assessment Test 5.4 Bypass and Purge Self-Assessment Test 5.5 The Industrial Application of Material Balances Summary Glossary Problems Part III: Gases, Vapors, and Liquids Chapter 6. Ideal and Real Gases Introduction 6.1 Ideal Gases Self-Assessment Test 6.2 Real Gases: Equations of State Self-Assessment Test 6.3 Real Gases: Compressibility Charts Self-Assessment Test 6.4 Real Gas Mixtures Self-Assessment Test Summary Glossary Supplementary References Problems Chapter 7. Multiphase Equilibrium 7.1 Introduction 7.2 Phase Diagrams and the Phase Rule Self-Assessment Test 7.3 Single-Component Two-Phase Systems (Vapor Pressure) Self-Assessment Test 7.4 Two-Component Gas/Single-Component Liquid Systems Self-Assessment Test Self-Assessment Test Self-Assessment Test 7.5 Two-Component Gas/Two-Component Liquid Systems Self-Assessment Test 7.6 Multicomponent Vapor-Liquid Equilibrium Summary Glossary Supplementary References Web Site Problems Part IV: Energy Balances Chapter 8. Energy Balances without Reaction Introduction 8.1 Terminology Associated with Energy Balances Self-Assessment Test 8.2 Overview of Types of Energy and Energy Balances Self-Assessment Test 8.3 Energy Balances for Closed, Unsteady-State Systems Self-Assessment Test Self-Assessment Test Self-Assessment Test Self-Assessment Test 8.4 Energy Balances for Open, Steady-State Systems Self-Assessment Test Self-Assessment Test Self-Assessment Test Self-Assessment Test 8.5 Mechanical Energy Balances Self-Assessment Test Self-Assessment Test Self-Assessment Test 8.6 Energy Balances for Special Cases Self-Assessment Test Summary Glossary Supplemental References Web Sites Problems Chapter 9. Energy Balances with Reaction Introduction 9.1 The Standard Heat (Enthalpy) of Formation Self-Assessment Test 9.2 The Heat (Enthalpy) of Reaction Self-Assessment Test 9.3 Integration of Heat of Formation and Sensible Heat Self-Assessment Test 9.4 The Heat (Enthalpy) of Combustion Self-Assessment Test Summary Glossary Supplemental References Web Sites Problems Part V: Combined Material and Energy Balances Chapter 10. Humidity (Psychrometric) Charts Introduction 10.1 Terminology Self-Assessment Test 10.2 The Humidity (Psychrometric) Chart Frequently Asked Questions Self-Assessment Test 10.3 Applications of the Humidity Chart Self-Assessment Test Summary Glossary Supplementary References Web Sites Chapter 11. Unsteady-State Material and Energy Balances Introduction 11.1 Unsteady-State Balances Self-Assessment Test 11.2 Numerical Integration of ODEs Self-Assessment Test 11.3 Examples Supplementary References Web Sites Glossary Problems Chapter 12. Heats of Solution and Mixing Looking Ahead 12.1 Heats of Solution, Dissolution, and Mixing Self-Assessment Test 12.2 Introducing the Effects of Mixing into the Energy Balance Self-Assessment Test Looking Back Glossary Supplementary References Web Sites Problems Chapter 13. Liquids and Gases in Equilibrium with Solids Looking Ahead 13.1 Main Concepts Self-Assessment Test Glossary Supplementary References Chapter 14. Solving Material and Energy Balances using Process Simulators (Flowsheeting Codes) Looking Ahead 14.1 Main Concepts Looking Back Supplementary References Part VI: Supplementary material Appendixes Appendix A. Atomic Weights and Numbers Appendix B. Tables of the Pitzer Z0 and Z1 Factors Appendix C. Heats of Formation and Combustion Appendix D. Answers to Selected Problems Appendix E. Physical Properties of Various Organic and Inorganic Substances Appendix F. Heat Capacity Equations Appendix G. Vapor Pressures Appendix H. Heats of Solution and Dilution Appendix I. Enthalpy-Concentration Data Appendix J. Thermodynamic Charts Appendix K. Physical Properties of Petroleum Fractions Appendix L. Solution of Sets of Equations L.1 Independent Linear Equations L.2 Nonlinear Independent Equations Supplementary Reference Appendix M. Fitting Functions to Data Index Code Snippets