Functional Polymers for Metal-Ion Batteries

Description

Functional Polymers for Metal-Ion Batteries Unique and useful book covering fundamental knowledge and practical applications of polymer materials in energy storage systems In Functional Polymers for Metal-Ion Batteries , the recent development and achievements of polymer-based materials are comprehensively analyzed in four directions, including electrode materials, binders, separators, and solid electrolytes, highlighting the working mechanisms, classification, design strategies, and practical applications of these polymer materials in mental-ion batteries. Specific sample topics covered in Functional Polymers for Metal-Ion Batteries include: Prominent advantages of various solid-state electrolytes, such as low flammability, easy processability, more tolerance to vibration, shock, and mechanical deformation. Why and how functional polymers present opportunities to maximize energy density and pursue the sustainability of the battery industry. How the application of functional polymers in metal-ion batteries helps enhance the high energy density of energy storage devices and reduce carbon footprint during production. How development of functional separators could significantly lower the cost of battery manufacturing. Providing a comprehensive understanding of the role of polymers in the whole configuration of metal-ion batteries from electrodes to electrolytes, Functional Polymers for Metal-Ion Batteries is an ideal resource for materials scientists, electrochemists, and polymer, solid state, and physical chemists who wish to understand the latest developments of this technology. Cover Half Title Functional Polymers for Metal-ion Batteries Copyright Contents About the Editors About the Contributors Introduction References 1. Polymeric Electrode Materials in Modern Metal‐ion Batteries 1.1 Introduction 1.2 Classification of PEMs 1.2.1 Carbonyls 1.2.2 Organosulfur 1.2.3 Organic Nitrogen (N) 1.2.4 Conducting Polymers 1.2.5 Organic Radicals 1.2.6 Superlithiated Compounds 1.3 Molecular Engineering of PEMs 1.3.1 Specific Energy Density 1.3.2 Power Density 1.3.3 Cycle Performance 1.4 Morphological Engineering of PEMs 1.4.1 0D PEMs 1.4.2 1D PEMs 1.4.3 2D PEMs 1.4.4 3D PEMs 1.5 Applications of PEMs 1.5.1 LIBs 1.5.2 SIBs 1.5.3 PIBs 1.5.4 Multivalent MIBs 1.5.4.1 Conducting Polymers 1.5.4.2 Carbonyl Compounds 1.5.4.3 Imine Compounds 1.6 Conclusion and Perspectives 1.6.1 Conclusion 1.6.2 Perspectives References 2. Polymeric Binders in Modern Metal-ion Batteries 2.1 Introduction 2.2 General Binding Mechanisms 2.3 Classification of Binders 2.4 Strategies of Binder Design 2.4.1 Strategies to Enhance Mechanical Interlocking 2.4.2 Strategies to Enhance Interfacial Bonding 2.4.3 Binders with Multiple Functionalities 2.5 Application of Binders for Different Energy Materials 2.5.1 High‐Voltage Cathodes 2.5.2 Li–S Batteries 2.5.3 Silicon Anode 2.5.4 Sodium‐Ion Batteries 2.5.5 Sodium–Sulfur and Potassium–Sulfur Batteries 2.6 Conclusion and Perspective References 3. Polymeric Separator in Modern Metal-ion Batteries 3.1 Introduction 3.2 Functions of Polymeric Separators in Metal‐ion Batteries 3.2.1 Essential Properties of Polymeric Separators 3.2.1.1 Porosity 3.2.1.2 Wettability 3.2.1.3 Strength 3.2.1.4 Thickness 3.2.2 Desirable Functions of Polymeric Separators 3.3 Classification of Polymeric Separators 3.3.1 Nonwoven Separators 3.3.2 Nanoporous Membrane Separators 3.3.3 Microporous Membrane Separators 3.3.4 Composite Membrane Separators 3.4 Functional Polymeric Separators for Modern Metal‐ion Batteries 3.4.1 Thermal‐resistant Separators 3.4.2 Reversible Thermally Induced Shutdown Separators 3.4.3 Separators for Metal Dendrite Growth Inhibition 3.4.4 Separators for Stopping the Shuttle Effect 3.4.5 Stretchable Separators for Flexible Batteries 3.4.6 The Separator as Li Source for Recycling Degraded Cathode 3.4.7 Super Wettable Separator to Boost Ionic Diffusion 3.5 Manufacturing Techniques of Polymeric Separators 3.5.1 Conventional Manufacturing Techniques of Polymeric Separators 3.5.2 Modern Manufacturing Techniques of Functional Polymeric Separators 3.6 Conclusion and Perspectives References 4. Polymeric Electrolytes in Modern Metal-ion Batteries 4.1 Introduction 4.2 Ion Transport in Polymeric Electrolytes 4.2.1 Solid Polymeric Electrolytes 4.2.2 Gel Polymeric Electrolytes 4.2.3 Composite Polymeric Electrolytes 4.3 Property Study 4.3.1 Thermal Analysis 4.3.2 Structural Analysis 4.3.3 Diffraction Technique 4.3.4 Conductivity Measurement 4.3.5 Nuclear Magnetic Resonance (NMR) 4.3.6 Modeling and Theory 4.4 Classifications of Polymeric Electrolytes 4.4.1 Solid Polymer Electrolytes 4.4.1.1 Dispersed Solid Polymer Electrolytes 4.4.1.2 Intercalated/Exfoliated Solid Polymer Electrolytes 4.4.1.3 Liquid Crystal Containing Polymer Electrolytes 4.4.2 Gel Polymer Electrolytes 4.4.2.1 Ionic‐Liquid‐based Polymer Electrolytes 4.4.2.2 Gel Polymer Electrolytes 4.5 Strategies in Designing Solid‐state Electrolytes 4.5.1 Pure Polymeric Electrolytes 4.5.1.1 Classification of Pure Solid Polymer Electrolytes 4.5.1.2 Composition of Pure Solid Polymer Electrolytes 4.5.1.3 Polymer Hosts 4.5.1.4 Conductive Salt 4.5.1.5 Research Strategy 4.5.2 Gel Polymeric Electrolyte 4.5.2.1 Component 4.5.2.2 Polymer Matrix 4.5.2.3 Plasticizer 4.5.2.4 Conductive Lithium Salt 4.5.3 Polymeric–Ceramic Composite Electrolyte 4.5.3.1 Components of Polymer–Ceramic Composite Electrolytes 4.5.3.2 Classification of Polymer–Ceramic Composite Electrolytes 4.5.3.3 Research Strategy 4.6 Application of Polymer Electrolytes in All‐solid‐state Batteries 4.6.1 Lithium Battery System 4.6.2 Sodium Battery System 4.6.3 Li‐S Battery System 4.7 Summary and Prospect References Index