The Al2SiO5 Polymorphs

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Page 1 Titles REVIEWS IN MINERALOGY Volume 22 THE AI2SiOs POLYMORPHS DERRILL M. KERRICK Page 1 Page 2 Page 1 Titles THE AI2SiOs POLYMORPHS TABLE OF CONTENTS Page 2 Page 3 Page 4 Page 5 Titles x Page 6 Page 7 Page 1 Page 2 Titles 2 )~) _, X '. r ,', ,1,' \ 1&1 f ;,' '. E § .: \ (2) ~ ' ... DALYT '. Page 3 Page 4 Titles 4 z Tables Table 1 Page 5 Page 6 Titles 6 Page 7 Titles 7 Page 8 Titles 8 t a.. Andolusite Sillimanite T- Page 9 Page 10 Titles 10 Tables Table 1 Page 11 Titles 11 Page 12 Titles 12 Page 1 Page 2 Titles 14 Page 3 Titles 15 c Page 4 Titles 16 ... ;( '" ;( '" ;( '" ;( '" ;( '" C'! --.- ~.:!..:!. -"'''' ....j....j....j --.- .:!.~,£!. "'", :C! ~C! .... 88 ...; . "'CO> ~~ "'''' ~~ '" ~ I I .r,; e ~ c .~ o » c.:::: Page 5 Titles ---- ,. ,. Page 6 Titles 18 Dispersion: r , "'. 1-, " Page 9 Page 10 Tables Table 1 Page 11 Titles 47 Page 12 Titles Temperature. °c Tables Table 1 Table 2 Table 3 Page 13 Page 14 Titles 50 . r~#/ .~ .... "'" /' 7 f.!,,:~.; ................. .... ..... ... Page 15 Titles ti, ~ 51 Page 16 Titles 52 Page 17 Titles +100 r----~---~---~_, (a) = o~----~------~----~~ = = µg K s T (OC) Tables Table 1 Table 2 Page 18 Titles 54 Page 19 Tables Table 1 Page 20 Titles 56 Tables Table 1 Page 21 Titles 57 Page 22 Tables Table 1 Page 23 Titles - Page 24 Titles 60 Tables Table 1 Page 25 Page 26 Titles 62 Page 27 Titles 63 Page 28 Titles 64 8 E kb2 , KYANITE // // £, /I' A;;//' SILLIMANITE 450 550 650 750 850 [3.2] Page 29 Page 30 Titles 66 Tables Table 1 Table 2 Page 31 Page 32 Tables Table 1 Page 33 Titles 69 K s Tables Table 1 Page 34 Titles 70 Page 35 Titles 71 Page 36 Titles 72 , .. ------- ---- ................... " ...... ... , "'" ... ... . , • Tables Table 1 REV022C003_p73-110.pdf Page 1 Titles 73 Page 2 Titles 74 Page 3 Titles 75 1000 s 900 700 800 T (0C) B 600 8 Tables Table 1 Page 4 Titles 76 Page 5 Titles 77 Page 6 Tables Table 1 Table 2 Page 7 Titles 79 Page 8 Titles 80 Page 9 Titles 81 Page 10 Titles 82 Page 11 Titles 83 " " Page 12 Titles 84 Page 13 Titles 85 Page 14 Tables Table 1 Page 15 Titles 87 Page 16 Page 17 Titles 89 (J) Page 18 Titles 90 • Page 19 Titles 91 Tables Table 1 Page 20 Titles 92 Page 21 Titles 93 Page 22 Titles 94 and sill Page 23 Titles 95 Page 24 Tables Table 1 Page 25 Titles 97 Page 26 Tables Table 1 Page 27 Titles • .. " Page 28 Page 29 Tables Table 1 Page 30 Titles 102 Page 31 Titles 103 P (Kbar) • s Sill 500 Page 32 Titles 104 II. P (Kbar) Page 33 Titles 105 Page 34 Titles 106 Page 35 Page 36 Titles 108 - .c - e en en ... Q. I Bohlen et al. (1989) • This Study Temperature CC) Page 37 Page 38 Page 1 Page 2 Titles 112 (a) (b) T-O-T. 0. 0. T-O-T. ~ p. }- Oc-T, ........ T a. Page 3 Titles 113 Page 4 Titles 114 > Z w o COMPOSITION o-s TEMPERATURE. C.:f'::' .:' Field ":'7;':": • • co 3 a.. Page 5 Titles 115 Page 6 Titles Wt x SiO, 116 6 o " Lf 4 s-e 'i 0 • 38 36 a 2 32 30 2-8 0'5 b o x Tables Table 1 Page 7 Titles 117 0'9 ~------------------ Tables Table 1 Page 8 Page 9 Titles 119 Page 10 Page 11 Page 12 Page 13 Page 14 Titles • • • '900 +--.----,.---.----,--...l...;-- I I I ~ q , IR IA1- Tables Table 1 Table 2 Page 15 Page 16 Tables Table 1 Page 17 Titles 127 o ~ a: a: b --x- Tables Table 1 Page 18 Titles 128 Page 19 Titles 129 KAN II ,) Tables Table 1 Table 2 Page 20 Tables Table 1 Page 21 Page 22 Titles 132 I / J.. J. I • • ~ I rlJ -l.. rlJ I ~ Page 23 Page 24 Page 25 Titles , Page 26 Titles 136 s . ' ° 2 ... ...... ' .. Tables Table 1 Page 27 Page 28 Titles 138 o x Tables Table 1 Page 29 Titles . - Page 30 REV022C004_p141-168.pdf Page 1 Titles 141 Tables Table 1 Page 2 Page 3 Page 4 Page 5 Titles 145 atom Fe/AI· ... . .. _. •• it •. . , .. . .IOt"I·_:t· .. ~ _ • • to- .... 8. ... e •• , . ••• 8 •• 0 .: .. ,:1 ••• : 0+,: 0 1 Page 6 Titles 146 Page 7 Titles LEGEND Tables Table 1 Page 8 Titles 148 a. Rio Mora b. Truchas Peaks slope = 0.92 slope = 106 • / • c. Truchas Peaks /~ slope = 0.49 o~----~------~-- Page 9 Page 10 Titles 150 ~ . .. . ... ~. . . .. ... '+ f.. Page 11 Titles 151 P Page 12 Titles 152 Page 13 Page 14 Titles 154 Snyder o 05 ~ ~t~~~ ~ ' .. ' "",~~i glapa i t ""_"_~'~.'".:'" I I 356 ~.'. ~88 196) , 8300 1\ e19' ~~_~_R~ \ - e81 I ~ l ezsa I en I CD \ « Page 15 Titles 155 DISTANCE (meters) 60 S ~ Tables Table 1 Page 16 Titles 156 Page 17 Titles 157 - ~ :6 T (K) so. ,~ ... .. t 2mm Page 18 Titles 158 o colourless D light blue Page 19 Page 20 Titles 160 Page 21 Titles a b •• ., '.. , ....... .... ...- .', .'. ...••..• Tables Table 1 Table 2 Page 22 Page 23 Titles 163 Page 24 Page 25 Page 26 Titles 166 Page 27 Page 28 Page 1 Page 2 Titles , , Page 3 Titles 171 Page 4 Titles 172 Page 5 Titles 173 I ... \ Page 6 Page 7 Page 8 Titles 176 ,,/"\ L0910 0 is Loeat i on Dens i ty , , a \ \ \. -, , B 2f- g Page 9 Page 10 Page 11 Titles 179 Tables Table 1 Page 12 Tables Table 1 Page 13 Page 14 Titles // Tables Table 1 Page 15 Titles 183 Page 16 Page 17 Page 18 Page 1 Titles ~s = R[2 In 2 - {(1 + s) In (1 + s) + (l - s) In (l - s)}] , [6.1] Page 2 Page 3 Tables Table 1 Page 4 Titles 190 18 12 ~ ::.::: 6 1600 1200 400 800 Deg. C Tables Table 1 Page 5 Titles 191 Page 6 Titles 192 Tables Table 1 Page 7 Page 8 Titles : / o Page 9 Titles 195 Page 10 Titles 196 Page 11 Titles 197 , ------- ~~ -------+---1 Page 12 Page 13 Page 14 Page 15 Page 16 Tables Table 1 Page 17 Titles 1 1 l Page 18 Titles 204 Tables Table 1 Page 19 Titles GUFFEY 205 BRANDYWINE PPM Figure 6.10. MAS-NMR spectra of fibrolite. Page 20 Page 1 Page 2 Page 3 Page 4 Tables Table 1 Page 5 Page 6 Titles 212 '" 3 • •.•• ·z ·zzz • • I •••• ·zz • ..... .. o co ..... :I: Page 7 Page 8 Page 9 Titles .. 215 Tables Table 1 Page 10 Page 11 Page 12 Titles e , , Page 13 Titles 219 e E (J/mol) 1000 D'AMETER (Microns) Page 14 Titles 220 Page 15 Page 16 Page 1 Page 2 Titles 224 Page 3 Page 4 Titles 226 Page 5 Titles 227 Tables Table 1 Page 6 Titles 228 Page 7 Titles 229 a b Page 8 Page 9 Page 10 Page 11 Titles 233 o Page 12 Page 13 Titles 235 - ,/' o . - - - - Page 14 Titles 236 Page 15 Page 16 Page 17 Page 18 Titles 240 / Tables Table 1 Page 19 Titles o~----~------~------._----~---- Tables Table 1 Page 20 Titles -. ------------- .. ---~~:::~ Page 21 Page 22 Titles 244 , / . , Page 23 Page 24 Titles 246 Page 25 Titles 247 Page 26 Titles 248 Page 27 Page 28 Titles 250 o Tables Table 1 Page 29 Page 30 Titles 252 • • Page 31 Page 32 Page 33 Page 34 Page 1 Page 2 Page 3 Page 4 Page 5 Titles o Page 6 Titles 262 Page 7 Titles 263 Page 8 Page 9 Titles 265 LEGEND (a) " • • Ad""''''' Page 10 Titles 266 Page 11 Page 12 Page 13 Titles 269 - Page 14 Titles 270 Page 15 Page 16 Page 17 Titles 273 Page 18 Page 19 Titles 275 ----- Distance (Km) Page 20 Page 21 Titles 277 Page 22 Titles + + + + + Page 23 Titles 8 p 6 4 2 ,. I 400 500 600 700 279 and\.sil p • * • /'. *. ,/'" • /-Ii'* • _ .. -. ~ .> Page 24 Page 25 Page 26 Titles 282 EXPLANATION y [Figure 9.15 legend: see opposite page] S,f,A Tables Table 1 Page 27 Titles 283 ... ... ... ... ... ... ... ... ... + + + + ... ... ... / I I I K Mt. o o N Page 28 Titles 284 o • • • + :j: + + • • o """,1-\ 1 I ? o o 1 + + o o o • o o o ~ o &l 0 +* ,1 ~O I~ ",1-\ * 1 I Gb I I -y I 0 0 d ~ ! 0 ? 4: I $ I 1 .t + + + REV022C009_p285-310.pdf Page 1 Titles 285 Page 2 Titles 286 :; e '" ,S E '" '" -5 12.....:. e~ ~E ., ~ ~ , ., - - ... '" ... ... ,_ '" Tables Table 1 Table 2 Page 3 Page 4 Titles TEMPERATURE (OCl TEMPERATURE (·e) Tables Table 1 Table 2 Page 5 Page 6 Titles T °c " " " , T °c Tables Table 1 Page 7 Page 8 Titles 292 I I r ,,····4 7" I I I I ~ I I I I I I I Tables Table 1 Page 9 Titles 293 Page 10 Page 11 Titles 295 Page 12 Titles 296 Page 13 Titles 297 Page 14 Titles 298 Page 15 Titles 299 s ..... c,.,.r., ".", • Tables Table 1 Table 2 Table 3 Page 16 Titles 300 Page 17 Page 18 Page 19 Page 20 Page 21 Titles 110 1'10 :T ;l~ITfT I. .. '151 ~ .. ~ ·10·.'. 7·.·.·.' ; , , , r.,.,." .,.,'0. "o·g·, ',0 ~OG .·.·'0· ~ I~ ·8-----------~ ~------5? • • 5------..., ~t !I' ~ , ; t . ' • flO Page 22 Page 23 Page 24 Titles 308 Page 25 Titles 309 Page 26 Titles 310 Page 1 Page 2 Page 3 Titles 313 Page 4 Titles 314 -z - 7",000 , .. zoo '" stated by Eugster (1970), suppression of sillimanite nuclei can be defended 2 K -feldspar + 2 H+ = Sillimanite + 5 Quartz + 2 K + + H20. Page 5 Page 6 Titles 316 Page 7 Page 8 Titles 318 CORE (A)j (C)l --t6I'> +",0 -: f~Fe(OH'> ---~t--------------fc~~- Page 9 Page 10 Titles 320 E-8 o Control Log t, yr o Tables Table 1 Page 11 Page 12 Page 13 Titles 323 Page 14 Titles 324 NET REACTION IN ROCK: Page 15 Page 16 Page 17 Titles 327 Page 18 Page 19 Page 20 Page 21 Titles • FIBROLITElSILLIMANITE r INSUBAIC LINE 331 •• o Page 22 Page 23 Titles r _._._._.-., ......................... .......... ~~., ~ ---------~ -----~----~ 333 Page 24 Titles 334 2. ,. ,. 6. •• Page 25 Titles 335 Page 26 Titles 336 T Gst. Rand- Rkt.- Qz ~ 50 o Kern- Zone Page 27 Titles 337 Kem / Rkt- Disthen Quarz Plagioklas Biotit Granat Sta.rolith Muscovit IOrrm Rand­ Gestein 1.111.. ,I. ,II", Page 28 Titles o~':t& @(g~ ..... i:: '''''''.'''.'.' .. '.'.'' .. ''.''_'''''. Tables Table 1 Page 29 Page 30 Page 31 Titles 341 Tables Table 1 Page 32 Titles 342 Page 33 Page 34 Titles 344 Page 35 Page 36 Titles 346 ~ '" Page 37 Titles 347 Page 38 Page 39 Titles 349 Tables Table 1 Table 2 Table 3 Page 40 Page 41 Titles '·'1·· . ;'.:::~ :/.\ A Page 42 Page 1 Page 2 Page 3 Titles 355 Ky - .~ .. .-:T -,. - - - Cd- - - - - ... ~ , ' ... H P kbar Tables Table 1 Page 4 Page 5 Page 6 Titles 358 K s Page 7 Page 8 Page 9 Page 10