Uranium - Mineralogy, Geochemistry, and the Environment

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Page 1 Titles URANIUM: Mineralogy, Geochemistry and the Environment Editors: Peter C. Burns! & Robert Finch" Page 1 Titles MINERALOGICAL SOCIETY OF AMERICA REVIEWS IN MINERALOGY Volume 38 URANIUM: Mineralogy, Geochemistry and the Environment ISBN 0-939950-50-2 ADDITIONAL COPIES of this volume as well as others in Page 1 Titles - URANIUM- Mineralogy, Geochemistry and the Environment FOREWORD Pau[ J{. t](j66e PREFACE Page 2 Titles !l(p6ert Finch. Page 1 Titles - URANIUM- Mineralogy, Geochemistry and the Environment Tables Table 1 Page 1 Titles TABLE OF CONTENTS 1 Radioactivity and the 20th Century 2 The Crystal Chemistry of Uranium Page 2 Titles 3 Systematics and Paragenesis of Uranium Minerals 4 Stable Isotope Geochemistry of Uranium Deposits Page 3 Titles 5 Environmental Aqueous Geochemistry of Actinides Page 4 Titles 7 Mineralogy and Geochemistry of Janusz Janeczek Page 5 Titles 8 Geomicrobiology of Uranium Page 6 Titles 9 Uranium Contamination in the Subsurface: 10 Uranium Mineralogy and the Geologic Page 7 Titles 12 Page 8 Titles 13 Analytical Methods for Determination of Uranium in Geological and Environmental Materials Page 9 Titles 14 Identification of Uranium-bearing Minerals and Inorganic Phases by X-ray Powder Diffraction Page 10 Page 1 Titles 1 Radioactivity and the 20th Century INTRODUCTION Page 2 Page 3 Page 4 Page 5 Titles 5 Page 6 Page 7 Titles Ewing: Radioactivity and the 20th Century 7 ex. y 1 ~ ~ (2) Page 8 Page 9 Page 10 Page 11 Page 12 Titles 12 URANIUM: Mineralogy, Geochemistry and the Environment Page 13 Titles 13 -----. Page 14 Page 15 Titles 15 Tables Table 1 Page 16 Titles 16 URANIUM: Mineralogy, Geochemistry and the Environment Page 17 Titles iii 'x .~ Time (years) Page 18 Titles 18 URANIUM: Mineralogy, Geochemistry and the Environment Tables Table 1 Page 19 Titles Ewing: Radioactivity and the 20th Century 19 ACKNOWLEDGMENTS REFERENCES Page 20 Titles 20 URANIUM: Mineralogy, Geochemistry and the Environment Page 21 Titles Ewing: Radioactivity and the 20th Century 21 Page 22 Page 1 Titles 2 The Crystal Chemistry of Uranium Page 2 Titles 24 Tables Table 1 Page 3 Titles I 1 1 1 I 1 Page 4 Page 5 Titles Burns: The Crystal Chemistry of Uranium Page 6 Tables Table 1 Page 7 Titles Burns: The Crystal Chemistry of Uranium Tables Table 1 Page 8 Page 9 Titles Burns: The Crystal Chemistry of Uranium 31 Tables Table 1 Table 2 Table 3 Page 10 Titles (c) Page 11 Page 12 Tables Table 1 Page 13 Titles (c) Page 14 Titles URANIUM: Mineralogy, Geochemistry and the Environment H R p R U P URDP DRUP Page 15 Titles (a) Burns: The Crystal Chemistry of Uranium (b) Tables Table 1 Page 16 Titles ....-- o - Page 17 Titles Burns: The Crystal Chemistry of Uranium Page 18 Titles T ..c 1 ~ ro Page 19 Titles Burns: The Crystal Chemistry of Uranium Anion topologies with triangles and pentagons Tables Table 1 Page 20 Page 21 Page 22 Titles 44 I 1 T o 1 T 1 Page 23 Titles I 1 r 1 1 .S Page 24 Page 25 Page 26 Titles I 1 1 1 " '" '" " '" • '" '" '" '" " .' '" " " • - o --- 1 1 1 1 Page 27 Titles I c 1 1 a 1 ~---------b----------~ 49 Page 28 Page 29 Tables Table 1 Page 30 Titles (e) Page 31 Titles f-..Q-j I-..Q-l --. ..0 -- T o 1 -r o 1 Page 32 Titles 54 URANIUM: Mineralogy, Geochemistry and the Environment T (II1~ (l:~ \------ c --\ f-- csinp----I T 1 Page 33 Titles Burns: The Crystal Chemistry of Uranium I a 1 I b 1 i-csinj)-l Page 34 Titles J---- a ----{ T b 1 REV038C002_p57-90.pdf Page 1 Page 2 Titles Q~ '-" Page 3 Titles (a) 1 c 1 (c) T csinp 1 (b) T a 1 a I-- b----i Page 4 Titles 60 \ ,/ / (b) Page 5 Titles • 1 1 • '" "" • • I 1 • • 1 j • ...- o -- Tables Table 1 Page 6 Titles r i 1 I 1 CQ. ro Page 7 Titles Burns: The Crystal Chemistry of Uranium 1 I b 1 Page 8 Page 9 Titles (a) urn Burns: The Crystal Chemistry of Uranium / Page 10 Titles URANIUM: Mineralogy, Geochemistry and the Environment Tables Table 1 Page 11 Titles Burns: The Crystal Chemistry of Uranium Page 12 Titles ---- ~ ~:~;~:*;~:¥';~ ---- e~ Page 13 Titles I a 1 Page 14 Titles T 1 T o 1 I----...c ------i f----...c Page 15 Page 16 Tables Table 1 Page 17 Titles I m i f o 1 1 m 1 Page 18 Titles 74 (e) T asin~ 1 (f) ~bsina---1 \-bsinY-\ Page 19 Titles Burns: The Crystal Chemistry of Uranium 75 Page 20 Titles ...- o -- 1--..0--1 I o 1 I--ro--l Page 21 Titles Burns: The Crystal Chemistry of Uranium T a 1 Tables Table 1 Page 22 Titles (b) Page 23 Titles Burns: The Crystal Chemistry of Uranium (a) c • • • • • • • • • • • ••••••••• ~ • • • • • • • • • • • ••••••••• • • • • • • • • • • I--a-l Tables Table 1 Page 24 Titles 80 (e) Page 25 Titles ...- o -- T ro 1 1 ...- -- T ro 1 I 1 T 'en 1 Page 26 Titles (g) I--- b sine -----1 Page 27 Titles Burns: The Crystal Chemistry of Uranium Tables Table 1 Page 28 Page 29 Tables Table 1 Page 30 Titles 86 URANIUM: Mineralogy, Geochemistry and the Environment (b) t---b------i T a 1 f------a----i f-------c-----J 1 a 1 (a) I b 1 ACKNOWLEDGMENTS REFERENCES Page 31 Titles Burns: The Crystal Chemistry of Uranium 87 Page 32 Titles 88 URANIUM: Mineralogy, Geochemistry and the Environment Page 33 Page 34 Titles 90 URANIUM: Mineralogy, Geochemistry and the Environment Page 1 Titles 3 Systematics and Paragenesis Robert Finch Takashi Murakami Page 2 Titles URANIUM MINERALS SYSTEMATICS Page 3 Page 4 Titles e ~ .~ ] Tables Table 1 Page 5 Page 6 Page 7 Titles Finch & Murakami: Systematics, Paragenesis of U Minerals 97 Page 8 Page 9 Titles Finch & Murakami: Systematics, Paragenesis of U Minerals 99 Page 10 Titles 100 URANIUM: Mineralogy, Geochemistry and the Environment M02 AB04 AB206 Lay.r 1 Lay.r 2 Lay.r 3 Lay.r 4 8-_lt. ••• '''. ••• "" ..... • THE «-Pb02 AND II 81 • Layer 5 Layer 6 Layer 7 Page 11 Titles Finch & Murakami: Systematics, Paragenesis of U Minerals 101 AB04 AB206 THE MIXED COORDINATION Wi!b lIi!b II •... , •. , , 18 •.. , " • " '. ". layer 1 layer 2 Layer 3 Layer 4 layer 5 Layer 6 Layer 7 Page 12 Titles t 2 2 2 .:;} ~ ~ ~ ~ t -5 ~ 6 6 6 E-. t.;:: I':: f- M : L.{-··-·. :: 1 fl§;;.-- .. -i: I : ! 'I I : / oJ =. ..... - ,. I 1 /0 .>: / .r.r . / / ./ L-r-J : / e. '+ / ,/ /' .L§'I 0 Poland Page 16 Page 17 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 197 STABLE ISOTOPIC STUDIES OF URANIUM DEPOSITS Page 18 Titles I 1060 1020 N ~ L. Page 19 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 199 Page 20 Titles ---------- ----------- Page 21 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 201 8 S Tables Table 1 Page 22 Page 23 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 203 o BEDDED VEIN OR VUG SULPHIDES .__if .. KOONGARRA RANGER JABILUKA I AND 2 Page 24 Titles o • • • -10 • o Page 25 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 205 Page 26 Titles • • .- Page 27 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 207 a b :: n. : : : : , , I' .: ~" , .4_ ·"'1"1 ,i : Tables Table 1 Page 28 Titles , , , , - , ~ .. Page 29 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 209 , , :+:+:+~ , Page 30 Titles . aTvl~r::l~ I o ,4 Page 31 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 211 """"""'" o ", ~ , -- ----+----'-r--/ \:~ .r, _ _j 'i: \~ Tables Table 1 Page 32 Titles c s ., ~ ~ ., ~ Page 33 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 213 Page 34 Titles 214 URANIUM: Mineralogy, Geochemistry and the Environment CONCLUSIONS ACKNOWLEDGMENTS REFERENCES Page 35 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 215 Page 36 Titles 216 URANIUM: Mineralogy, Geochemistry and the Environment Page 37 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 217 Page 38 Titles 218 URANIUM: Mineralogy, Geochemistry and the Environment Page 39 Titles Fayek & Kyser: Stable Isotope Geochemistry of Uranium Deposits 219 Page 40 Titles 220 URANIUM: Mineralogy, Geochemistry and the Environment Page 1 Titles 5 Environmental Aqueous Geochemistry William M. Murphy Everett L. Shock INTRODUCTION Page 2 Titles GENERALITIES OF ENVIRONMENTAL AQUEOUS Page 3 Titles Complications in environmental aqueous actinide geochemistry Page 4 Titles 224 URANIUM: Mineralogy, Geochemistry and the Environment Page 5 Page 6 Titles Uranium and other actinides in hot water Page 7 Titles