Recent Advances in Applications of Name Reactions in Multicomponent Reactions
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Recent Advances in Applications of Name Reactions in Multicomponent Reactions is an ideal reference for researchers and postgraduate students studying organic chemistry, as well as synthetic organic chemists working on the development of novel methodologies for the synthesis of various heterocyclic systems, especially drug design and discovery, in both academia and industry. The book reviews recent applications of name reactions in multicomponents for the synthesis of heterocycles and examines recent advances in applications of significant name reactions, such as Ugi and Passirini, Click, Knoevenagel, Michael, Diels-Alder, Aldol, Mannich, Heck, Huisgen, and Suzuki in MCRs. These reactions can be used in the synthesis of a wide variety of novel heterocycles with different sizes and heteroatoms, as well as in the total synthesis of natural products in order to decrease the number of synthetic steps. Since chiral inductions are necessary for most of these sequential name reactions, their asymmetric catalyzed reactions are also described. Chapter Introduction 1.1 - Introduction 1.1.1 - Multicomponent reactions (MCRs) 1.1.2 - General conception 1.1.3 - Green chemistry 1.1.4 - Name reactions 1.2 - Summary and outlook References Chapter Direct synthesis of heterocycles via MCRs, using a name reaction 2.1 - Biginelli reaction 2.2 - Hantzsch reaction 2.3 - Click reaction 2.4 - Gewald reaction 2.5 - Ugi reaction and Ugi-azide reaction 2.5.1 - Ugi-azide reaction References Chapter Synthesis of heterocycles via MCRs, using a name reaction in combination with another reaction Anchor 666 3.1 - Michael addition reaction 3.2 - Mannich reaction 3.3 - Aldol reaction 3.4 - Knovenagel reaction 3.5 - Wittig reaction References Chapter Multicomponent reaction via combinations of name reactions 4.1 - Knoevenagel condensation/Michael addition 4.2 - Knoevenagel condensation/Pinner reaction 4.3 - Knoevenagel-type/aza-Diels-Alder 4.4 - Michael addition/Henry reaction 4.5 - Michael type coupling/Knoevenagel reaction 4.6 - Triple-domino Michael/aza-Henry/cyclization reaction 4.7 - Michael addition/Mannich reaction 4.8 - Ugi-4CR/Wittig reaction 4.9 - Ugi/Smiles coupling 4.10 - Ugi-Smiles coupling/intramolecular Diels-Alder cycloaddition 4.11 - Ugi/aza-Wittig reaction 4.12 - Ugi four-component /Povarov-type reaction 4.13 - Joullie-Ugi reaction 4.14 - Click reaction/aldol condensation 4.15 - Knovenagel condensation/click reaction 4.16 - Click reaction/Knoevenagel condensation 4.17 - Sonogashira cross-coupling reaction/Micheal addition 4.18 - Baylis-Hillman/Click reaction 4.19 - Aldol condensation/Michael-type addition 4.20 - Baylis-Hillman type addition/Michael addition 4.21 - Biginelli reactions/Click reaction 4.22 - Micheal addition/Ullman reaction 4.23 - Click reaction/Biginelli reaction 4.24 - Knoevenagel condensation/Hantzsch-like reaction 4.25 - Adol condensation/Michael addition 4.26 - Michael addition/Henry reaction 4.27 - Aldol condensation/Michael addition 4.28 - Aldol condensation/Michael addition 4.29 - Aldol condensation/Michael addition References Chapter Asymmetric multicomponent reactions 5.1 - Introduction 5.2 - Asymmetric Bignelli reaction 5.2.1 - Using chiral catalysts 5.2.2 - Using chiral catalys 5.3 - Asymmetric Ugi reaction 5.4 - Asymmetric Povarov reaction 5.5 - Asymmetric Diels-Alder reaction 5.6 - Asymmetric Mannich reaction 5.7 - Asymmetric Michael addition reaction 5.8 - Asymmetric Aldol reaction 5.9 - Miscellaneous asymmetric reactions References
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