ENGLISH

The Effective Crystal Field Potential

By Jacek Mulak and Zbigneiew Gajek (Auth.)

Book information

Publisher
Elsevier
Year
2000
ISBN
978-0-08-043608-1
Language
english
Format
PDF
Filesize
4 MB (3742358 bytes)
Pages
294\294
Time added
2013-09-14 05:30:00

Description

Content: Preface, Pages v-viiChapter 1 - Introduction, Pages 1-9Chapter 2 - Parameterization of crystal field Hamiltonian, Pages 11-29Chapter 3 - The effective crystal field potential. Chronological development of crystal field models, Pages 31-40Chapter 4 - Ionic complex or quasi-molecular cluster. Generalized product function, Pages 41-52Chapter 5 - Point Charge Model (PCM), Pages 53-63Chapter 6 - One-configurational model with neglecting the non-orthogonality. The charge penetration and exchange effects, Pages 65-75Chapter 7 - The exclusion model. One-configurational approach with regard to non-orthogonality of the wave functions, Pages 77-89Chapter 8 - Covalency contribution, i.e. the charge transfer effect, Pages 91-103Chapter 9 - Schielding and antishielding effect: Contributions from closed electron shells, Pages 105-117Chapter 10 - Electrostatic crystal field contributions with consistent multipolar effects. Polarization, Pages 119-129Chapter 11 - Crystal field effect in the Stevens perturbation approach, Pages 131-142Chapter 12 - Specific mechanisms of metallic state contributing to the crystal field potential, Pages 143-145Chapter 13 - Screening the crystal field in metallic materials, Pages 147-162Chapter 14 - Virtual bound state contribution to the crystal field potential, Pages 163-176Chapter 15 - Hybridization or covalent mixing between localized states and conduction band states in metallic crystals, Pages 177-184Chapter 16 - Density functional theory approach, Pages 185-209Chapter 17 - Analysis of the experimental data. Interpretation of crystal field parameters with additive models, Pages 211-228Chapter 18 - Lattice Dynamics Contribution, Pages 229-245Chapter 19 - Extension of the crystal field potential beyond the one-electron model, Pages 247-256Chapter 20 - Appendices, Pages 257-261References, Pages 263-286Author Index, Pages 287-292Subject Index, Pages 293-303

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