ENGLISH

S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II

By Norbert Baumann , Hans-Jürgen Fachmann , Reimund Jotter , Alfons Kubny (auth.) , Alfons Kubny (eds.)

Book information

Publisher
Springer-Verlag Berlin Heidelberg
Year
1994
ISBN
978-3-662-06353-8, 978-3-662-06351-4
DOI
10.1007/978-3-662-06351-4
Language
english
Format
PDF
Filesize
9 MB (9019379 bytes)
Series
Gmelin Handbook of Inorganic and Organometallic Chemistry / Gmelin Handbuch der Anorganischen Chemie S / S-N / 10 / a : S. Schwefel. Sulfur (System-Nr. 9)
Edition
8
Pages
324\347
Time added
2013-12-12 02:00:00
Gmelin

Description

This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by Ä2 + 4Ü cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only ÄS=N=SÜ+AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium salts. Thiohydroxylamine, HSNH2, has been detected in the gas phase. Numerous examples of N,N-diorganyl-amino-halogeno-sulfanes (XSNR2, X = F, Cl, Br, I; R = organyl) and salts of the cation (XS)2N+ (X = Cl, Br) are known. N,N-Diorganyl-amino-chloro-sulfanes are important synthetic reagents.

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