Comprehensive Organometallic Chemistry IV

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Cover Half Title Comprehensive Organometallic Chemistry IV. Volume 2: Group 1 to 2 Copyright Contents of Volume 2 Editor Biogrphies Contributors to Volume 2 Preface 2.01 Introduction to Groups 1 to 2 Refrences 2.02 Organometallic Complexes of the Alkali Metals Abbreviations 2.02.1. Introduction 2.02.2. Structural diversity of alkali metal organometallics 2.02.2.1. Alkyl derivatives 2.02.2.1.1. Methyl, propyl and butyl 2.02.2.1.2. Secondary and tertiary alkyl derivatives 2.02.2.1.3. Benzyl, diphenyl, and triphenylmethane derivatives 2.02.2.1.4. Silyl substituted alkyl derivatives 2.02.2.1.5. Phosphorus and sulfur substituted alkyl derivatives 2.02.2.2. Aryl derivatives 2.02.2.3. Cyclopentadienide, indenide and fluorenide derivatives 2.02.2.4. Alkali metal interactions with π-systems 2.02.2.5. Alkynyl derivatives 2.02.2.6. Ylide, yldiide, and methandiide derivatives 2.02.2.7. Metallocene derivatives 2.02.3. Assessing aggregation of alkali metal organometallics using NMR spectroscopy 2.02.3.1. DOSY NMR studies 2.02.3.2. Solution constitution of lithium amides 2.02.4. Mixed alkyl/alkoxide aggregates of alkali metals 2.02.5. Summary References 2.03 Organometallic Complexes of the Alkaline Earth Metals Abbreviations 2.03.1. Introduction 2.03.2. Beryllium 2.03.2.1. Aryl and allyl compounds 2.03.2.2. Carbene stabilized organoberyllium compounds 2.03.2.2.1. N-Heterocyclic carbene (NHC) stabilized beryllium compounds 2.03.2.2.2. Cyclic (alkyl) (amino) carbene (CAAC) stabilized organoberyllium compounds 2.03.2.2.2.1. CAAC-stabilized low-oxidation state organoberyllium compounds 2.03.2.2.2.2. CAAC stabilized neutral radicals and radical cations 2.03.2.2.2.3. Reactivity of CAAC stabilized beryllium dihalide compounds 2.03.2.2.3. Carbodicarbene stabilized organoberyllium compounds 2.03.2.2.4. Synthesis of carbodiphosphorane-stabilized organoberyllium compounds with a metal-carbon double bond 2.03.2.3. Organoberyllium compounds with group 15 donor ligands 2.03.2.3.1. N-donor stabilized organoberyllium compounds 2.03.2.3.2. P-donor stabilized organoberyllium compounds 2.03.2.4. Miscellaneous compounds 2.03.3. Magnesium 2.03.3.1. Organocyclopentadienyl derivatives of magnesium 2.03.3.2. Carbene stabilized organomagnesium compounds 2.03.3.2.1. `Normal NHC coordinated organomagnesium compounds 2.03.3.2.2. `Abnormal NHC-supported organomagnesium compounds 2.03.3.2.3. CAAC-stabilized organomagnesium compounds 2.03.3.2.4. Alkoxy-functionalized NHC-stabilized organomagnesium compounds 2.03.3.2.5. Amido-functionalized NHC-stabilized organomagnesium compounds 2.03.3.3. Organomagnesium compounds with group 15 bonded ligands 2.03.3.3.1. Synthesis of N-donor ligand supported four, five, and six-membered ring organomagnesium compounds 2.03.3.3.2. Synthesis of high-membered rings and mixed-donor (N, O, and N, P, etc.) supported homoleptic and heteroleptic ... 2.03.3.3.3. Synthesis of mixed metal organomagnesium compounds 2.03.3.3.4. Chiral organomagnesium compounds related to N-donor ligands 2.03.3.3.5. Other N-donor organomagnesium compounds 2.03.3.3.6. Preparation of organomagnesium compounds by using low oxidation state Mg(I) complexes 2.03.3.3.7. Preparation of organomagnesium compounds by using BDIMg(II) hydride 2.03.3.3.8. Magnesiation of simple organic compounds 2.03.3.4. Organomagnesium compounds with oxygen bonded ligands 2.03.3.5. Cationic organomagnesium complexes 2.03.3.5.1. Group-14 stabilized organomagnesium cationic compounds 2.03.3.5.2. Group-15 stabilized organomagnesium cationic compounds 2.03.3.6. Organomagnesium π-arene complexes 2.03.3.7. Application of organomagnesium complexes as catalysts 2.03.4. Calcium 2.03.4.1. C-donor stabilized organocalcium compounds 2.03.4.1.1. Alkyl stabilized organocalcium compounds 2.03.4.1.2. Aryl stabilized organocalcium compounds 2.03.4.1.3. NHC stabilized organocalcium alkyls 2.03.4.1.4. NHC stabilized organocalcium amides/halides 2.03.4.2. Cyclopentadienyl stabilized organocalcium compounds 2.03.4.3. N-donor stabilized organocalcium compounds 2.03.4.3.1. β-Diketiminate stabilized organocalcium compounds 2.03.4.3.2. Tp stabilized organocalcium compounds 2.03.4.3.3. Pincer stabilized organocalcium compounds 2.03.4.4. Cationic organocalcium compounds 2.03.4.5. Mixed metal organocalcium compounds 2.03.4.6. π-Arene stabilized organocalcium compounds 2.03.4.7. Applications of organocalcium complexes as catalysts 2.03.5. Strontium and barium 2.03.5.1. Alkyl and alkynyl compounds 2.03.5.2. Carbene stabilized strontium and barium organometallic complexes 2.03.5.2.1. NHC stabilized compounds 2.03.5.2.2. CAAC supported compounds 2.03.5.2.3. Bis-iminophosphorano barium carbene complexes 2.03.5.3. Cyclopentadienyl derivatives of strontium and barium 2.03.5.4. Group 15 ligand supported organometallic compounds 2.03.5.4.1. N-donor ligand supported four, five, and six-membered ring organostrontium compounds 2.03.5.4.2. Tp ligand supported organobarium complexes 2.03.5.4.3. Miscellaneous N-donor ligand stabilized organostrontium compounds 2.03.5.4.4. Chiral N-donor ligand stabilized organobarium compounds 2.03.5.5. Cationic organostrontium and barium complexes 2.03.5.6. Heterobimetallic organostrontium and barium compounds 2.03.5.7. Organometallic (MSr and Ba) π Arene complexes 2.03.6. Concluding remarks Acknowledgment References Cover back