Ruthenium Chemistry

Description

Content: Cover Half Title Title Page Copyright Page Table of Contents Preface 1: An Introduction to Ruthenium Chemistry 2: Ruthenium in Medicinal Chemistry 2.1 Introduction 2.1.1 General Remarks 2.1.2 Ruthenium Compounds Potentiality as Prospective Drugs 2.2 Ruthenium Antitumoral Compounds 2.2.1 Classic Coordination Compounds 2.2.2 Organometallic Compounds 2.3 Ruthenium Antiparasitic Compounds 2.3.1 Ruthenium Compounds against Trypanosomatid Parasites 2.3.2 Ruthenium Compounds against Malaria Parasites 2.4 Concluding Remarks and Perspectives 3: An Overview of Ruthenium Complexes as a Potential Sensing Agent3.1 Introduction 3.2 Sensing Property of Ruthenium Complexes 3.3 Ruthenium Complexes as Cation Sensor 3.4 Ruthenium Complexes an Anion Sensor 3.4.1 Anion Sensing through Acidic Hydrogen 3.4.2 Anion Sensing through Lewis Acidic Sites 3.4.3 Anion Sensing through Chemodosimeter Approach 3.5 Ruthenium Complexes as Gas Sensor 3.6 Ruthenium Complexes as Sensing Agent of Neutral Species 3.6.1 Detection of Amino Acids 3.6.2 Detection of DNA Molecule 3.6.3 Detection of Other Biomolecules 3.6.4 Detection of Hazardous Compounds3.7 pH Sensing 3.8 Temperature Sensing 3.9 Conclusion and Perspective 4: Ruthenium Compounds: A New Approach in Nanochemistry 4.1 Introduction 4.2 Synthesis of Metallic Nanoparticles 4.2.1 Physical Method 4.2.2 Chemical Method 4.2.3 Wet Chemical Synthesis 4.3 Applications of Ru Nanoparticles 4.3.1 Catalytic Application 4.3.1.1 Oxidation 4.3.1.2 Reduction 4.3.1.3 Hydrolysis 4.3.1.4 Hydrogenolysis 4.3.1.5 Olefin metathesis 4.3.1.6 Isotope exchange 4.3.1.7 Miscellaneous catalytic reactions 4.3.2 As Analytical Tool 4.3.3 Biomedical Applications4.4 Future Prospects 4.5 Conclusions 5: Synthesis and Characterization of Copperâ#x80 #x93 Ruthenium Composites 5.1 Introduction to Microelectronic Packaging Material 5.2 Ruthenium as Emerging Material 5.2.1 Early History of Ruthenium 5.2.2 Rutheniumâ#x80 #x93 Aluminum Alloy 5.3 History of Copper 5.3.1 Ruthenium as Diffusion Barrier in Copper Interconnect 5.3.2 Ruthenium as Alloying Element for Thermal Management Materials 5.3.3 Ruthenium as Oxidation Resistance for Copper 5.4 Processing Techniques of Metal Reinforced with Ruthenium 5.4.1 Powder Metallurgy 5.4.2 Overview of Sintering Process5.4.3 Spark Plasma Sintering Technique 5.4.4 Sintering of Ruthenium Alloy 5.5 Properties of Ruthenium Alloy 5.5.1 Properties of Copper with Ruthenium Additive 5.5.2 Properties of WC-Co with Ruthenium Additive 5.6 Properties of Ruthenium Oxide 5.6.1 Properties of RuO2 for Supercapacitor Applications 5.7 Conclusion 6: Orbital Tuning of Ruthenium Polyimine Complexes by Ligand Design: From Basic Principles to Applications 6.1 Basic Principles of Orbital Tuning for Ruthenium Polyimine Complexes 6.1.1 Ruthenium Polyimine Complexes