ENGLISH

The elements of polymer science and engineering an introductory text and reference for engineers and chemists

Book information

Publisher
Academic Press
Year
1999
ISBN
9780126016857, 0126016852
Language
english
Format
PDF
Filesize
23 MB (23930312 bytes)
Edition
2
Pages
\529
Time added
2020-04-16 21:06:07

Description

The Elements of Polymer Science and Engineering Copyright Page Contents Preface Chapter 1. Introductory Concepts and Definitions 1.1 Some Definitions 1.2 Degree of Polymerization 1.3 Polymerization and Functionality 1.4 Why Are Synthetic Polymers Useful? 1.5 Copolymers 1.6 Molecular Architecture 1.7 Thermoplastics and Thermosets 1.8 Elastorncrs, Fibers, and Plastics 1.9 Miscellaneous Terms 1.10 Polymer Nomenclature Problems References Chapter 2. Basic Principles of Polymer Molecular Weights 2.1 Importance of Molecular Weight Control 2.2 Plan of This Chapter 2.3 Arithmetic Mean 2.4 Molecular Weight Averages as Ratios of Moments 2.5 Breadth of the Distribution 2.6 Summarizing the Molecular Weight Distribution 2.7 Mz >= Mw >= Mn 2.8 Integral and Summative Expressions 2.9 Direct Measurements of Average Molecular Weights 2.10 Colligative Properties and Mn 2.11 Virial Equations 2.12 Virial Coefficients Problems Reference Chapter 3. Practical Aspects of Molecular Weight Measurements 3.1 Mn Methods 3.2 Light Scattering 3.3 Dilute Solution Viscometry 3.4 Size Exclusion Chromatography Problems Reference Chapter 4. Effects of Polymer Isomerism and Conformational Changes 4.1 Constitutional Isomerism 4.2 Conligurational Isomerism 4.3 Polymer Conformation 4.4 Molecular Dimensions in the Amorphous State 4.5 Rubber Elasticity 4.6 Rodlike Macrontoleculcs Problems Reference Chapter 5. Step-Growth Polymerizations 5.1 Condensation and Addition Polymers 5.2 Step-Growth and Chain-Growth Polynicrizations 5.3 Requirents for Step-Growth Polyinerization 5.4 Polymer Size and Extent of Conversion of Functional Groups in Equilibrium Step-Growth Polymerizations 5.5 Interfacial and Solution Polymerizations of Acid Chlorides and Other Reactive Monomers 5.6 Step-Growth Copolymerizations Problems Reference Chapter 6. Free-Radical Polymerization 6.1 scope 6.2 Polymerizability of Monomers 6.3 Overall Kinetics of Radical Polymerization 6.4 A Note on Termination Rate Constants 6.5 Methods of Producing Radicals 6.6 Length of the Kinetic Chain and Number Average Degree of Polymerization of the Polymer 6.7 Modes of Termination 6.8 Chain Transfer 6.9 Inhibition and Retardation 6.10 Readily Observable Features of Free-Radical Polymerizations 6.11 Radical Lifetimes and Concentrations 6.12 Determination of kp and kt 6.13 Deviations from Ideal Kinetics 6.14 Molecular Weight Distribution 6.15 Free-Radical Techniques for Polymers with Narrower Molecular Weight Distributions 6.16 Effects of Temperature 6.17 Free-Radical Polymerization Processes Problems Reference Chapter 7. Copolymerization 7.1 Chain-Growth Copolymerization 7.2 Simple Copolymer Equation 7.3 Copolymer Structure Inferences from Feactivity Ratios 7.4 Azeotropic Compositions 7.5 Integrated Binary Copolymer Equation 7.6 Determination or Reactivity Ratios 7.7 Multicomponent Copolyinerizations 7.8 Sequence Distribution in Copolymers 7.9 Gel Forination During Copolytnerization and Cross-Linking 7.10 Kcactivities of lladicals and Monomers 7.11 Analysis of Reactivity Data 7.12 Effect of Rcaction Conditions 7.13 Rates of Free-Radical Copolymerizations 7.14 Alternative Copolymerization Models Problems Reference Chapter 8. Dispersion and Emulsion Polymerizations 8.1 Dispersion Polymerization 8.2 Emulsion Polymerization 8.3 Other Ingredients in Emulsion Recipes 8.4 Emulsion Polymerization Processes Problems Referece Chapter 9. Ionic and Coordinated Polymerizations 9.1 Comparison of Ionic and Free-Radical Polymerizations 9.2 Anionic Polymerization 9.3 Group Transfer Polymerization 9.4 Cationic Polymerization 9.5 Coordination Polymerization 9.6 Olefin Metathesis Catalysts Problems Reference Chapter 10. Polymer Reaction Engineering 10.1 scope 10.2 Step-Growth Polymerizations 10.3 Chain-Growth Polymerizations 10.4 Homogeneous and Heterogeneous Polymerization Processes 10.5 Batch, Semibatch, and Continuous Processes 10.6 Polymerization Reactors Problems Reference Chapter 11. Mechanical Properties of Polymer Solids and Liquids 11.1 Introduction 11.2 Thermal Transitions 11.3 Crystallization of Polymers 11.4 The Glass Transition 11.5 Polymer Viscoelasticity 11.6 Dynamic Mechanical Behavior at Thermal Transitions 11.7 Stress–Strain Tests 11.8 Crazing in Glassy Polymers 11.9 Fracture Mechanics 11.10 Toughness and Brittleness 11.11 Rheology 11.12 Effects of Fabrication Processes Problems Reference Chapter 12. Polymer Mixtures 12.1 Compatibility 12.2 Thermodynamic Theories 12.3 Solvents and Plasticizers 12.4 Fractionation 12.5 Practical Aspects of Polymer Blending 12.6 Reinforced Elastomers 12.7 Reinforced Plastics Problems Reference Appendix A. Conversion of Units Appendix B. List of Symbols Index

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