ENGLISH

Stereoselective Organocatalysis: Bond Formation Methodologies and Activation Modes

Book information

Year
2013
ISBN
9781118203538, 9781118604755
DOI
10.1002/9781118604755
Language
english
Format
PDF
Filesize
26 MB (27335312 bytes)
Pages
674\674
Orientation
yes
Scanned
yes
Time added
2013-08-01 04:00:00

Description

Sets forth an important group of environmentally friendly organic reactionsWith contributions from leading international experts in organic synthesis, this book presents all the most important methodologies for stereoselective organocatalysis, fully examining both the activation mode as well as the type of bond formed. Clear explanations guide researchers through all the most important methods used to form key chemical bonds, including carbon-carbon (C?C), carbon-nitrogen (C?N), and carbon-halogen (C?X) bonds. Moreover, readers will discover how the use of non-metallic catalysts facilitates a broad range of important reactions that are environmentally friendly and fully meet the standards of green chemistry. Stereoselective Organocatalysis begins with an historical overview and a review of activation modes in asymmetric organocatalysis. The next group of chapters is organized by bond type, making it easy to find bonds according to their applications. The first of these chapters takes a detailed look at the many routes to C?C bond formation. Next, the book covers: Organocatalytic C?N bond formationC?O bond formationC?X bond formationC?S, C?Se, and C?B bond formationEnantioselective organocatalytic reductionsCascade reactions forming both C?C bonds and C?heteroatom bondsThe final chapter is devoted to the use of organocatalysis for the synthesis of natural products. All the chapters in the book are extensively referenced, serving as a gateway to the growing body of original research reports and reviews in the field. Based on the most recent findings and practices in organic synthesis, Stereoselective Organocatalysis equips synthetic chemists with a group of organocatalytic reactions that will help them design green reactions and overcome many challenges in organic synthesis.Content: Chapter 1 Introduction: A Historical Point of View (pages 1–10): Ramon Rios and Xavier CompanyoChapter 2 Activation Modes In Asymmetric Organocatalysis (pages 11–80): Albert MoyanoChapter 3 C–C Bond Formation by Aldol Reaction (pages 81 –127): Dorota Gryko and Dominika WalaszekChapter 4 Examples of Metal?Free Direct Catalytic Asymmetric Mannich?Type Reactions Using Aminocatalysis (pages 129 –146): Armando CordovaChapter 5 C?C Bond Formation by Michael Reaction (pages 147 –203): Yong Zhang and Wei WangChapter 6 C?C Bond Formation By Diels–Alder and Other Pericyclic Reactions (pages 205 –229): Johan FranzeenChapter 7 N?Heterocyclic Carbene?Catalyzed C–C Bond Formation (pages 231 –266): Xiang?Yu Chen and Song YeChapter 8 ??Alkylation of Carbonyl Compounds (pages 267 –312): Marek Remes and Jan VeselyChapter 9 Other Reactions For C–C Bond Formation (pages 313 –350): Yi?Xia Jia and Tiexin ZhangChapter 10 Cascade Reactions Forming C–C Bonds (pages 351 –380): Ramon Rios, Jorge Esteban and Xavier CompanyoChapter 11 Organocatalytic C?N Bond Formation (pages 381–431): Aitor Landa, Rosa Lopez, Antonia Mielgo, Mikel Oiarbide and Claudio PalomoChapter 12 C–O Bond Formation (pages 433 –463): Jose Alemaan and Mariola TortosaChapter 13 Carbon–Halogen Bond Formation (pages 465–492): Stacey E. Brenner?MoyerChapter 14 C–Other Atom Bond Formation (S, Se, B) (pages 493–527): Giorgio Della Sala and Alessandra LattanziChapter 15 Enantioselective Organocatalytic Reductions (pages 529 –558): Maurizio Benaglia, Martina Bonsignore and Andrea GenoniChapter 16 Cascade Reactions Forming Both C–C Bond and C–Heteroatom BOND (pages 559–585): Damien Bonne, Thierry Constantieux, Yoann Coquerel and Jean RodriguezChapter 17 Organocatalysis in the Synthesis of Natural Products (pages 587 –628): Yongcheng Ying and Xuefeng Jiang

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