Inorganic Reactions and Methods: Formation of Bonds to C, Si, Ge, Sn, Pb (Part 3), Volume 11
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Content: Chapter 5.5.1 Introduction (pages 1–3): J. J. Zuckerman and E K StormsChapter 5.5.2.2. From Lithium and its Alloys (pages 3–14): M. E. NewcombChapter 5.5.2.2.2. With Organomercurials (pages 14–17): M. E. NewcombChapter 5.5.2.2.3. With Adducts of Conjugated Hydrocarbons in Donor Solvents (pages 17–26): M. E. NewcombChapter 5.5.2.2.4. With Acidic Hydrocarbons Evolving H2 (pages 26–28): M. E. NewcombChapter 5.5.2.2.5. With Ethers, Amines, Sulfides and Phosphines Cleaving the Carbon?Element Bonds (pages 28–31): M. E. NewcombChapter 5.5.2.3. From Other Organolithiums (pages 31–44): J. L. WardellChapter 5.5.2.3.2. By Proton?Metal Exchange with Acidic C—H Bonds1?5 (pages 44–107): J. L. WardellChapter 5.5.2.3.3. By Halogen?Lithium Exchange with Organic Halides1?2 (pages 107–129): J. L. WardellChapter 5.5.2.3.4. By Addition of Organolithiums to Olefins or Acetylenes (pages 129–142): J. L. WardellChapter 5.5.2.3.5. By Action of Lithium Arene Radical Anions and Dianions (pages 142–147): J. L. WardellChapter 5.5.3. Carbon?Group?IA Bonds (page 148): E. K. StormsChapter 5.5.3.1.1. Giving NA Carbides (page 148): E. K. StormsChapter 5.5.3.1.2. Giving K, RB and CS Carbides (pages 148–149): E. K. StormsChapter 5.5.3.2. From the Group?IA Metals and their Alloys (pages 149–153): E. GrovensteinChapter 5.5.3.2.2. With Ethers (pages 153–157): E. GrovensteinChapter 5.5.3.2.3. With Organomercurials (pages 158–159): E. GrovensteinChapter 5.5.3.2.4. With Adducts of Conjugated Hydrocarbons in Donor Solvents (pages 160–164): E. GrovensteinChapter 5.5.3.2.5. With Acidic Hydrocarbons Evolving H2 (pages 164–166): E. GrovensteinChapter 5.5.3.2.6. By Cleavage of Carbon?Carbon Bonds (pages 167–171): E. GrovensteinChapter 5.5.3.3. From Other Group?IA Organometallics of the Same Metal (pages 171–175): M. E NewcombChapter 5.5.3.3.2. By Metal?Metal Exchange with Less Active Organometallics (page 175): M. E. NewcombChapter 5.5.3.3.3. By Addition to Olefins and Acetylenes (page 176): M. E. NewcombChapter 5.5.4. Silicon?Group?IA Bonds (page 177): J Y CoreyChapter 5.5.4.1. From the Elements (pages 177–178): J Y CoreyChapter 5.5.4.2. From Organodi? and Organopolysilanes (pages 178–181): J Y CoreyChapter 5.5.4.2.2. With Anionic Reagents (pages 181–183): J Y CoreyChapter 5.5.4.3. From Organohalosilanes with Alkali Metals (pages 183–184): J Y CoreyChapter 5.5.4.4. From Organosilicon Hydrides with Alkali Metals and Metal Hydrides (page 185): J Y CoreyChapter 5.5.4.5. From Tetraorganosilanes with Alkali Metals (pages 185–186): J Y CoreyChapter 5.5.4.6. From Silylmercurials (pages 186–187): J Y CoreyChapter 5.5.4.7. From Exchange (page 187): J Y CoreyChapter 5.5.5. Germanium?Group?IA Bonds (pages 187–188): J Y CoreyChapter 5.5.5.1. From the Elements (page 188): J Y CoreyChapter 5.5.5.2. From Organodigermanes (pages 188–190): J Y CoreyChapter 5.5.5.2.2. With Alkali?Metal Alkoxides and Organolithiums (page 191): J Y CoreyChapter 5.5.5.3. From Organohalogermanes with Alkali Metals (pages 191–192): J Y CoreyChapter 5.5.5.4. From Organogermanium Hydrides with Alkali Metals and Derivatives (pages 192–194): J Y CoreyChapter 5.5.5.5. From Tetraorganogermanes with Alkali Metals (pages 194–195): J Y CoreyChapter 5.5.5.6. From Germy?Mercury and ?Thallium with Alkali Metals (pages 195–196): J Y CoreyChapter 5.5.5.7. From Exchange and/or Ge(II) Derivatives (page 197): J Y CoreyChapter 5.5.6. Tin?Group?IA Bonds (pages 197–198): A. K. SawyerChapter 5.5.6.1. From the Elements (page 199): A. K. SawyerChapter 5.5.6.1.1. Lithium (page 199): A. K. SawyerChapter 5.5.6.1.2. Sodium (pages 199–200): A. K. SawyerChapter 5.5.6.1.3. Potassium (page 200): A. K. SawyerChapter 5.5.6.1.4. Rubidium (page 200): A. K. SawyerChapter 5.5.6.1.5. Cesium (page 200): A. K. SawyerChapter 5.5.6.2. From Organodistannanes with Alkali Metals (pages 200–202): A. K. SawyerChapter 5.5.6.2.2. Sodium (page 202): A. K. SawyerChapter 5.5.6.2.3. Potassium (page 203): A. K. SawyerChapter 5.5.6.3. From Organotin Halides with Alkali Metals (pages 203–204): A. K. SawyerChapter 5.5.6.3.2. Sodium (page 204): A. K. SawyerChapter 5.5.6.3.3. Potassium (page 204): A. K. SawyerChapter 5.5.6.4. From Organotin Hydrides with Alkali Metals (page 205): A. K. SawyerChapter 5.5.6.5. From Tetraorganotins with Alkali Metals (pages 205–206): A. K. SawyerChapter 5.5.6.6. From Tin(II) Compounds with Organoalkali Reagents (pages 206–207): A. K. SawyerChapter 5.5.7. Lead—Group?IA Bonds (page 207): F. Huber and K. GratzChapter 5.5.7.1.1. From the Elements (pages 207–209): F. Huber and K. GratzChapter 5.5.7.1.2. By Reduction (page 209): F. Huber and K. GratzChapter 5.5.7.1.3. By Electrolysis (pages 209–210): F. Huber and K. GratzChapter 5.5.7.2. From Hexaorganodiplumbanes (page 210): F. Huber and K. GratzChapter 5.5.7.2.1. With Alkali Metals (pages 210–211): F. Huber and K. GratzChapter 5.5.7.2.2. With Organoalkali Reagents (page 212): F. Huber and K. GratzChapter 5.5.7.3. From Tetraorganoleads with Alkali Metals (pages 212–213): F. Huber and K. GratzChapter 5.5.7.4. From Organolead Halides with Alkali Metals (pages 213–214): F. Huber and K. GratzChapter 5.5.7.5. From Lead(II) Compounds with Organoalkali Reagents (page 214): F. Huber and K. GratzChapter 5.5.7.6. By Miscellaneous Routes (page 214): F. Huber and K. GratzChapter 5.6.1 Introduction (pages 215–216): J. J. Zuckerman and F. GlocklingChapter 5.6.3. From the Group?IB Metals and Alloys (pages 216–217): G. Van KotenChapter 5.6.4. From the Metal Salts (pages 217–219): G. Van KotenChapter 5.6.4.1. By Metal–Metal Exchange with Another Organometallic (pages 219–229): G. Van KotenChapter 5.6.4.2. By Metal—Halogen Exchange (page 229): G. Van KotenChapter 5.6.4.3. By Metallation (pages 229–232): G. Van KotenChapter 5.6.4.4. By Insertion (pages 233–234): G. Van KotenChapter 5.6.4.5. By Addition, Decarboxylation (pages 234–235): G. Van KotenChapter 5.6.4.6. By Forming Adducts with Unsaturated Hydrocarbons (page 235): G. Van KotenChapter 5.6.5. From the Metal?Phosphine Complexes (page 236): F. GlocklingChapter 5.6.5.2. By Insertion (page 237): F. GlocklingChapter 5.6.5.3. By Transmetallation (page 237): F. GlocklingChapter 5.6.5.4. By Metal?Halide Exchange (page 237): F. GlocklingChapter 5.7.1 Introduction (pages 238–247): J. J. Zuckerman, E. K. Storms and J L WardellChapter 5.7.2.2.2. With Organomercurials (pages 247–248): J. L. WardellChapter 5.7.2.2.3. With Aryldiazonium Salts (page 248): J. L. WardellChapter 5.7.2.3. From Metal Salts (pages 248–270): J. L. WardellChapter 5.7.2.3.2. By Redistribution with the Organometallics of the Same Metal (pages 270–276): J. L. WardellChapter 5.7.2.3.3. By Addition to Olefins and Acetylenes or Cyclopropanes by Ring Opening (pages 277–301): J. L. WardellChapter 5.7.2.3.4. With Acidic Hydrocarbons (pages 302–318): J. L. WardellChapter 5.7.2.3.5. With Diazoalkanes (pages 318–320): J. L. WardellChapter 5.7.2.3.6. With Diazonium Salts (pages 320–323): J. L. WardellChapter 5.7.2.3.7. With Organosulfinic, Organosulfonic and oRganoboronic Acid Derivatives (pages 323–335): J. L. WardellChapter 5.7.2.4. From Other Group?IIB Organometallics of the Same Metal (pages 335–337): K.?H. ThieleChapter 5.7.2.4.2. By Olefin Insertion (pages 337–338): K.?H. ThieleChapter 5.7.2.4.3. By Metal?Metal Exchange with Other Organometallics (pages 339–340): K.?H. ThieleChapter 5.7.3. Silicon?Group?IIB Bonds (pages 340–341): F. GlocklingChapter 5.7.3.1. From Silyl?Alkali?Metal Reagents with Group?IIB Halides and Organohalides (pages 342–343): F. GlocklingChapter 5.7.3.2. From Organohalosilanes with Na or Al Amalgam (pages 343–344): F. GlocklingChapter 5.7.3.3. From Organosilicon Hydrides with Zn, Cd and Hg Dialkyls (pages 344–346): F. GlocklingChapter 5.7.3.4. From Silylcadmiums and ?Thalliums with Hg Metal (page 346): F. GlocklingChapter 5.7.3.5. From Redistribution and Related Reactions (pages 346–347): F. GlocklingChapter 5.7.4. Ge?Group?IIB Bonds (pages 347–348): F. GlocklingChapter 5.7.4.1. From Germyl–Alkali?Metal Reagents with Group?IIB Halides and Organohalides (page 348): F. GlocklingChapter 5.7.4.2. From Organogermanium Hydrides with Zn, Cd and Hg Dialkyls (pages 348–351): F. GlocklingChapter 5.7.4.3. From Organohalogermanes with Na Amalgam (pages 351–352): F. GlocklingChapter 5.7.4.4. From Germylcadmiums, ?Thalliums and ?Bismuths with Hg (page 352): F. GlocklingChapter 5.7.4.5. From Digermanes with Hg(II) Compounds (pages 352–353): F. GlocklingChapter 5.7.4.6. From Germyl–Group–IIB Compounds by Redistribution (page 353): F. GlocklingChapter 5.7.4.7. Form Silyl– or Germylmercurials and Ge(IV) Halides (page 354): F. GlocklingChapter 5.7.4.8. By Insertion of Germylenes into Hg—C or Hg—Ge Bonds (pages 354–355): F. GlocklingChapter 5.7.5. Tin?Group?IIB Bonds (pages 355–356): A. K. SawyerChapter 5.7.5.1. From the Elements (pages 356–357): A. K. SawyerChapter 5.7.5.1.2. With Cd (page 357): A. K. SawyerChapter 5.7.5.1.3. With Hg (page 357): A. K. SawyerChapter 5.7.5.2. From Organotin Hydrides with Zn, Cd and Hg Dialkyls (pages 358–359): A. K. SawyerChapter 5.7.5.2.2. With Cd Alkyls (pages 359–360): A. K. SawyerChapter 5.7.5.2.3. With Hg Alkyls (pages 360–362): A. K. SawyerChapter 5.7.5.3. From Organotin Halides with Germylmercurials (page 362): A. K. SawyerChapter 5.7.5.4. From Organotin Alkoxides with Silylmercurials (page 363): A. K. SawyerChapter 5.7.6. Lead—Group–IIB Bonds (page 364): F. Huber and K. GratzChapter 5.7.6.1.2. By Reduction (pages 364–365): F. Huber and K. GratzChapter 5.7.6.1.3. By Electrolysis (page 365): F. Huber and K. GratzChapter 5.7.6.2. In Organolead?Group?IIB Compounds (pages 365–366): F. Huber and K. Gratz
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