New Materials: Preparation, Properties and Applications in the Aspect of Nanotechnology

Description

This book covers a wide field of theoretical and experimental investigations of organic and inorganic systems: preparation methods, functional properties characterization and modification and practical applications. The first section includes studies in carbon structures of reduced dimensionality. Covered topics are: thermodynamic modeling of the behavior of fullerenes at heating in Argon, studying carbon nanotubes by X-ray diffraction, modelling of oscillating systems by cognitive digital systems. The number of chapters describes the structural investigations of a wide variety of materials such as different sorts of steel in grained modification for mining equipment, elements of rock-breaking, crushing and grinding equipment; degradation of dielectrics, including nanostructured dielectrics, by migratory polarization. Quantum chemical calculations were traditionally of a special interest of modelling nanostructured nuclei's. This method was applied to study titanium and vanadium nanocoating's formation from gas phase and to study quaternary ammonium compounds for modification of metal surfaces. Quantum-chemical calculations in bio-medical aspect made possible visualization ischemia-reperfusion injury using indocyanine green. The final paper in the section contains a scientific essay, where peculiarities of quantum mechanics are traversed through findings of nanotechnology. Section 2 includes the chapters related to preparation methods for the materials containing various components. It is opened by research of nanoporous alumina, which is a promising material for printed circuit boards. Heat flow distribution was found to possess some interesting features. Physical properties of electrochemically grown metallic filaments studied by electron microscopy anddiversity from dendritic to fractal structure was described. Fractal thematic was also addressed with simulation of breakdown in plasma channel. Section 3 is focused on the possibility of using new nanomaterials of different composition and design as powders for corundum ceramics, perfluorsulfonic membranes, refining noble methods from ultrafine valuable components, metals regeneration from oxide, and surface nanostructuring laser mechanisms. Mentoring aspect - education of the young researchers involved in nanoscience and technology -- is covered in chapter ""Students Training on ""Nanoengineering"", which is also a very important and promising scientific field. Contents Foreword Section 1. Theory and Modeling of Nanoprocesses Chapter 1 Modeling of Fullerenes C32 Heating in Argon: Thermodynamic Computer Experiment Abstract Introduction Method Experimental Section Conclusion References Chapter 2 Cluster Model of Graphitized Multi-Walled Carbon Nanotubes Abstract Introduction Method Experimental Section Conclusion References Chapter 3 Transformation Modeling of Nanostructures by Cognitive Systems According to Big Smart Data Abstract 1. Introduction 2. Cognitive Method Search of Regularities 2.1. Data Processing Languages 2.2. Digital Systems of Modeling 2.3. Cognitive Technology of Search of Regularities 3. Practical Approach to Modeling of Transformation of Nanostructures on the Basis of Big Smart Data Conclusion References Chapter 4 Grain Size Reduction in the Material Structure as an Effective Method of Increasing the Wear Resistance of Quick-Wear Elements of Mining Equipment Abstract Introduction Discussion Experimental Section Conclusion References Chapter 5 Degradation of Ionic Dielectrics under the Influence of Migratory Polarization Abstract Introduction Theoretical Model Experimental Section Conclusion References Chapter 6 Nanodiagnostics of Construction Materials Abstract Introduction Method Experimental Section Conclusion References Chapter 7 The Influence of the Relative Concentrations of VOCL3 and TiCL4 Vapors in the Gas Mixture on the Composition of Vanadium-Titanium-Containing Nanocoatings on the Silica Surface Abstract Introduction Method Experimental Section Conclusion References Chapter 8 Quantum-Chemical Modeling of Quaternary Ammonium Compounds for Modification of Metal Surface Abstract Introduction Materials and Methods Results and Discussion Conclusion References Chapter 9 Quantum-Chemical Justification of Using Indocyanine Green for Intravital Visualization of Ischemia-Reperfusion Injury Abstract Introduction Materials and Methods Results and Discussion Conclusion References Chapter 10 Spectral and Kinetic Parameters of Triplet States of Acylic Derivatives Polycyclic Hydrocarbon Abstract 1. Introduction 2. Materials and Methods 2.1. Chemicals 2.2. Experimental Methods 3. Results and Discussion 3.1. Triplet-Triplet Absorption Conclusion Acknowledgments References Chapter 11 Some Peculiarities of Nanoworld from the Position of Modern Quantum Mechanics Abstract Introduction Acknowledgments References Section 2. Physics of Nanoparticles and Nanomaterials Chapter 12 Thermal Flows in a PCB from Aluminum with Alumina Generated by a Linear Heat Source Abstract Introduction Method Experimental Section Conclusion Acknowledgment References Chapter 13 Using the Method of SEM Image Processing to Study the Morphology of Porous Anodic Alumina Films Abstract Introduction Method Experimental Section Conclusion Acknowledgment References Chapter 14 Radial Distribution of the Thermoelectric Parameters in BixSb2-xTe3 Solid Solution Produced by Hot Extrusion Abstract Introduction Experimental Procedures and Results Conclusion References Chapter 15 Nanoscale Range Metal’s Filamentous Powders of Cubic System Abstract Introduction Method Experimental Section Conclusion References Chapter 16 Characterization of Microplasma Breakdown in Semiconductor Structures Based on Fractal Analysis Abstract 1. Introduction 2. Materials and Methods 3. Results and Discussion Conclusion References Section 3. Functional Properties and Practical Applications Chapter 17 Activation of the Surface of Alumina Powders for Sintering Ceramics Abstract Introduction Method Experimental Section Conclusion Acknowledgment References Chapter 18 Porous Structure and Sorption Capacity of Perfluorosulfonic Membrane MF-4SK Abstract Introduction Experimental Section Preparation of Membranes Water Adsorption, Estimation of Specific Surface and Membrane Pore Volume Determination of Sulfur Groups Content in the Membrane Ion-Exchange Membrane Capacity Conclusion References Chapter 19 On the Use of Microwave Treatment of Gold-Containing Concentrates for Its Efficient Processing Abstract Introduction Materials and Methods Experimental Section Conclusion References Chapter 20 Regeneration of the Metal Oxidizer in the Near-Surface Layer as the Most Successful Variant of the Macrocycle in the Mechanism of Heterogeneous Heterophase Oxidation of the Metal Abstract Introduction Method Experimental Section Conclusion References Chapter 21 Research of Nanostructuring of Metal Surfaces by the Nanobar Code Processing Abstract Introduction Method Experimental Section Conclusion References Chapter 22 Raman Spectroscopy as a Method for Studying the Composition of Films of Compounds AiiBvi, AiiiBv on a Sic/Si Heterostructure Abstract Introduction Method Experimental Section Conclusion References Chapter 23 Mott-Schottky Analysis of Multi-Layered Graphenes for Application in Electrochemical Charge Storage Devices Abstract Introduction Graphenes Structure Materials and Methods Mott-Schottky Analysis Results and Discussion Comparison with Literature Measuring Electrical Conductivity by Four-Probe Method Scanning Transmission Microscopy Studies Conclusion References Chapter 24 Investigation the Absorption Spectra of Dialysate Output Line in the Hemodialysis Process to Create Biosensors Abstract Introduction Measurement Technique Results and Discussions Conclusion References Chapter 25 Professional Orientated Education System on Nanoengineering Abstract Introduction Method Experimental Section Conclusion References Editors’ Contact Information Index Blank Page