Spin-Crossover Materials: Properties and Applications
Book information
Description
The phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved.Spin-Crossover Materials: Properties and Applications presents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics includingSpin-crossover in mononuclear, polynuclear and polymeric complexesStructure: function relationships in molecular spin-crossover materialsCharge-transfer-induced spin-transitionsReversible spin-pairing in crystalline organic radicalsSpin-state switching in solutionSpin-crossover compounds in multifunctional switchable materials and nanotechnologyPhysical and theoretical methods for studying spin-crossover materialsSpin-Crossover Materials: Properties and Applications is a valuable resource for academic researchers working in the field of spin-crossover materials and topics related to crystal engineering, solid state chemistry and physics, and molecular materials. Postgraduate students will also find this book useful as a comprehensive introduction to the field.Content: Chapter 1 The Development of Spin?Crossover Research (pages 1–54): Keith S. MurrayChapter 2 Novel Mononuclear Spin?Crossover Complexes (pages 55–76): Birgit WeberChapter 3 Spin?Crossover in Discrete Polynuclear Complexes (pages 77–120): Juan Olguin and Sally BrookerChapter 4 Polymeric Spin?Crossover Materials (pages 121–146): M. Carmen Munoz and Jose Antonio RealChapter 5 Structure:Function Relationships in Molecular Spin?Crossover Materials (pages 147–169): Malcolm A. HalcrowChapter 6 Charge Transfer?Induced Spin?Transitions in Cyanometallate Materials (pages 171–202): Kim R. Dunbar, Catalina Achim and Michael ShatrukChapter 7 Valence Tautomeric Transitions in Cobalt?dioxolene Complexes (pages 203–224): Colette BoskovicChapter 8 Reversible Spin Pairing in Crystalline Organic Radicals (pages 225–237): Jeremy M. Rawson and John J. HaywardChapter 9 Breathing Crystals from Copper Nitroxyl Complexes (pages 239–280): Victor Ovcharenko and Elena BagryanskayaChapter 10 Spin?State Switching in Solution (pages 281–301): Matthew P. Shores, Christina M. Klug and Stephanie R. FiedlerChapter 11 Multifunctional Materials Combining Spin?Crossover with Conductivity and Magnetic Ordering (pages 303–319): Osamu Sato, Zhao?Yang Li, Zi?Shuo Yao, Soonchul Kang and Shinji KanegawaChapter 12 Amphiphilic and Liquid Crystalline Spin?Crossover Complexes (pages 321–345): Shinya HayamiChapter 13 Luminescent Spin?Crossover Materials (pages 347–373): Helena J. Shepherd, Carlos M. Quintero, Gabor Molnar, Lionel Salmon and Azzedine BousseksouChapter 14 Nanoparticles, Thin Films and Surface Patterns from Spin?Crossover Materials and Electrical Spin State Control (pages 375–404): Paulo Nuno Martinho, Cyril Rajnak and Mario RubenChapter 15 Ultrafast Studies of the Light?Induced Spin Change in Fe(II)?Polypyridine Complexes (pages 405–424): Majed CherguiChapter 16 Real?Time Observation of Spin?Transitions by Optical Microscopy (pages 425–441): Francois Varret, Christian Chong, Ahmed Slimani, Damien Garrot, Yann Garcia and Anil D. NaikChapter 17 Theoretical Prediction of Spin?Crossover at the Molecular Level (pages 443–454): Robert J. Deeth, Christopher M. Handley and Benjamin J. HoughtonChapter 18 Theoretical Descriptions of Spin?Transitions in Bulk Lattices (pages 455–474): Cristian Enachescu, Masamichi Nishino and Seiji MiyashitaChapter 19 Optimizing the Stability of Trapped Metastable Spin States (pages 475–506): Jean?Francois Letard, Guillaume Chastanet, Philippe Guionneau and Cedric DesplanchesChapter 20 Piezo? and Photo?Crystallography Applied to Spin?Crossover Materials (pages 507–526): Philippe Guionneau and Eric ColletChapter 21 Spin?Transitions in Metal Oxides (pages 527–541): Jean?Pascal Rueff
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