ENGLISH

S Sulfur-Nitrogen Compounds Part 8: Compounds with Sulfur of Oxidation Number IV

By Norbert Baumann , Hans-Jürgen Fachmann , Reimund Jotter , Alfons Kubny (eds.) , Brigitte Heibel , Birgit Ledüc (auth.)

Book information

Publisher
Springer-Verlag Berlin Heidelberg
Year
1991
ISBN
978-3-662-06365-1, 978-3-662-06363-7
DOI
10.1007/978-3-662-06363-7
Language
english
Format
PDF
Filesize
10 MB (10309231 bytes)
Series
Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition S / S-N / 8 : S. Schwefel. Sulfur (System-Nr. 9)
Edition
8
Pages
487\518
Time added
2014-01-18 08:00:00
Gmelin

Description

PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.

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