Solid Electrolytes for Advanced Applications: Garnets and Competitors
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This book highlights the state of the art in solid electrolytes, with particular emphasis on lithium garnets, electrolyte-electrode interfaces and all-solid-state batteries based on lithium garnets. Written by an international group of renowned experts, the book addresses how garnet-type solid electrolytes are contributing to the development of safe high energy density Li batteries. Unlike the flammable organic liquid electrolyte used in existing rechargeable Li batteries, garnet-type solid electrolytes are intrinsically chemically stable in contact with metallic lithium and potential positive electrodes, while offering reasonable Li conductivity. The book's respective chapters cover a broad spectrum of topics related to solid electrolytes, including interfacial engineering to resolve the electrolyte-electrode interfaces, the latest developments in the processing of thin and ultrathin lithium garnet membranes, and fabrication strategies for the high-performance solid-state batteries.This highly informative and intriguing book will appeal to postgraduate students and researchers at academic and industrial laboratories with an interest in the advancement of high energy-density lithium metal batteries Front Matter ....Pages i-viii Front Matter ....Pages 1-1 Solid-State Electrolytes: Structural Approach (Suresh Mulmi, Venkataraman Thangadurai)....Pages 3-24 Synthesis of Nanostructured Garnets (J. M. Weller, Candace K. Chan)....Pages 25-68 Air Stability of LLZO Electrolytes (Oluwatemitope Familoni, Ying Zhou, Huanan Duan)....Pages 69-89 Influence of Strain on Garnet-Type Electrolytes (Hirotoshi Yamada)....Pages 91-110 Sintering Additives for Garnet-Type Electrolytes (Nataly C. Rosero-Navarro, Kiyoharu Tadanaga)....Pages 111-128 Deposition and Compositional Analysis of Garnet Solid Electrolyte Thin Films (Sandra Lobe, Christian Dellen)....Pages 129-154 Ultrathin Garnet-Type Electrolytes (Xufeng Yan, Weiqiang Han)....Pages 155-166 Composite Electrolytes Based on Tetragonal Li7La3Zr2O12 for Lithium Batteries (E. A. Il’ina, S. V. Pershina)....Pages 167-193 Li7La3Zr2O12 and Poly(Ethylene Oxide) Based Composite Electrolytes (Frederieke Langer, Robert Kun, Julian Schwenzel)....Pages 195-215 Front Matter ....Pages 217-217 Zero-Strain Insertion Materials for All-Solid-State Li-Ion Batteries (Kazuhiko Mukai)....Pages 219-240 Interfacial Engineering for Lithium Metal Batteries Based on Garnet Structured Solid Fast Lithium-Ion Conductors (Mir Mehraj Ud Din, George V. Alexander, Ramaswamy Murugan)....Pages 241-273 Front Matter ....Pages 275-275 Grain Boundary Engineering for High Short-Circuit Tolerance (Rajendra Hongahally Basappa, Hirotoshi Yamada)....Pages 277-296 All-Solid-State Batteries Based on Glass-Ceramic Lithium Vanadate (Anton A. Raskovalov, Nailya S. Saetova)....Pages 297-334 Fabrication of All-Solid-State Lithium Batteries with an Aerosol Process (Takeshi Kimura, Kiyoshi Kanamura)....Pages 335-346 Li Metal Polymer Batteries (Ismael Gracia, Michel Armand, Devaraj Shanmukaraj)....Pages 347-373
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