Advanced Catalysts Based on Metal-organic Frameworks: Part 1

Description

Advanced Catalysts Based on Metal-organic Frameworks is a comprehensive introduction to advanced catalysts based on MOFs. It covers basic information about MOF catalysts with industrial and environmental applications. It updates readers on current applications and strategies to apply MOF-based catalysts in industrial processes geared for sustainability initiatives such as renewable energy, pollution control and combating carbon emission. Key Features - 13 structured, easy to read chapters that comprehensively cover MOF catalysts - An introduction to basic information about MOF catalysts - In-depth coverage of advanced applications of MOF catalysts - Explanation of MOF modifications and applications of derivative compounds - In-depth coverage of MOF catalysts used for electrocatalysis and photocatalysis - Detailed explanation of environmental-friendly and sustainable technologies (biomass upgrading, water purification, CO2 capture) - Updated references for advanced readers The is an essential reference for chemical engineers, scientists in the manufacturing and sustainability industry and post-graduate scholars working on MOFs and chemical catalysis. Cover Title Copyright End User License Agreement Contents Preface List of Contributors Strategies, Synthesis, and Applications of Metal-Organic Framework Materials Zuo-Xi Li1,* and Chunxian Guo1,2,3,* 1. INTRODUCTION OF METAL-ORGANIC FRAMEWORKS 2. SYNTHESIS OF MOFS 2.1. Raw Materials 2.1.1. Meal Nodes 2.1.2. Organic Linkers 2.1.3. Other Compositions 2.2. Synthesis Methods 2.2.1. Solution Methods (Stirring, Evaporation and Diffusion) 2.2.2. Hydrothermal Method (Water and Organic Solvents) 2.2.3. Ionthermal Method 2.2.4. Sublimation Method 2.2.5. Solid-State Reaction Method 2.2.6. Microwave-Assisted Synthesis 2.2.7. Sonochemical Synthesis 2.2.8. Electrochemical Synthesis 3. DESIGN STRATEGIES 3.1. Reticular Chemistry 3.2. Natural Mineral Structure Simulation 3.3. Stepwise Assembly 3.4. Synthesis of Homologues with the Same Frameworks 3.5. Postsynthetic Modification Strategy 4. APPLICATIONS 4.1. Adsorption and Separation 4.1.1. Gas Storage and Separation 4.1.2. Vapor Adsorption 4.1.3. Hazards and Pollutant Concentration in Solutions 4.2. Catalysis 4.2.1. Metal Nodes as Active Sites 4.2.2. Organic Ligands as Active Sites 4.2.3. Guests as Active Sites 4.3. Luminescence 4.3.1. Chemical Sensors 4.3.2. MOF-based LED Materials 4.3.3. Bioimaging 4.4. Drug Delivery CHALLENGES AND PERSPECTIVES/CONCLUSION CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES Post-synthetic Modification and Engineering of Metal Nodes and Organic Ligands of MOFs for Catalytic Applications Aleksander Ejsmont1, Agata Chełmińska1, Martyna Kotula1, Anita Kubiak1, Marcelina Kotschmarów1, Aleksandra Galarda1, Anna Olejnik1 and Joanna Goscianska1,* 1. INTRODUCTION 2. METAL-BASED POST-SYNTHETIC MODIFICATIONS OF MOFS 2.1. Transmetalation (Metal Exchange) 2.2. Metal Incorporation (Metal Doping) 2.3. Oxidation of the Coordination Site (Redox Transformations) 3. LIGAND-BASED POST-SYNTHETIC MODIFICATIONS OF MOFS 3.1. Ligand Functionalization 3.2. Ligand Exchange 3.3. Ligand Installation 3.4. Ligand Removal 4. TANDEM PSM OF MOFS 5. EPITAXIAL GROWTH ON MOFS CONCLUDING REMARKS LIST OF ABBREVIATIONS CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES MOFs and Their Composites as Catalysts for Organic Reactions Anna Olejnik1, Aleksandra Galarda1, Anita Kubiak1, Marcelina Kotschmarów1, Aleksander Ejsmont1, Agata Chełmińska1, Martyna Kotula1, Simona M. Coman2 and Joanna Goscianska1,* 1. INTRODUCTION 2. MOFS AND THEIR STABILITY 3. ACTIVE SITES IN MOF AND MOF COMPOSITE 4. MOFS AS CATALYSTS IN OXIDATION PROCESSES 4.1. Oxidation of Alkanes, Cycloalkanes and Alkylbenzenes 4.2. Oxidation of Alkenes and Cycloalkenes 4.3. Oxidation of Alcohols 4.4. Oxidation of Thiols and Sulfides 5. MOFS AS CATALYSTS FOR C–C COUPLING REACTIONS 6. MOFS AS CATALYSTS IN HYDROGENATION REACTIONS CONCLUDING REMARKS LIST OF ABBREVIATIONS CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES Metal-Organic Frameworks and Their Derived Structures for Biomass Upgrading Yushan Wu1, Yanfei Xu1, Chuan Qin1 and Mingyue Ding1,* 1. INTRODUCTION 1.1. Biomass 1.2. MOFs and MOFs-based Structures 1.3. Scope of this Chapter 2. BIOMASS CONVERSION OVER MOFS AND THEIR DERIVED STRUCTURES 2.1. Transformation of Cellulose Biomass 2.2. Conversion of C5 or C6 Sugars 2.2.1. Glucose Isomerization to Fructose 2.2.2. Conversion of C5/C6 Sugars to 5-Hydroxymethylfurfural (HMF) 2.2.3. Transformation of C5/C6 Sugars to other Feedstocks 2.3. Conversion of Platform Chemicals 2.3.1. Conversion of Levulinic Acid and its Derivates 2.3.2. Transformation of Alkyl Levulinates 2.3.3. Transformation of 5-Hydroxymethylfurfural (HMF) 2.3.4. Conversion of Furfural (FF) 3. TRANSFORMATION OF VANILLIN 4. CONCLUSIONS AND FUTURE PROSPECT LIST OF ABBREVIATIONS CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES MOF-Based Materials for CO2 Conversion Dinesh De1,*, Vivekanand Sharma2 and Mayank Gupta3 1. INTRODUCTION 2. SYNTHESIS OF VALUE-ADDED ORGANIC COMPOUNDS USING CO2 AS PRECURSOR 2.1. Conversion of CO2 into Cyclic Carbonates (CC) 2.1.1. CO2 Conversion into Cyclic Carbonates Using MOF Catalysts 2.1.2. CO2 Conversion into Cyclic Carbonates Catalyzed by MOF Composites 2.1.3. CO2 Conversion into Cyclic Carbonates Using MOF Derivatives 2.2. Fixation of CO2 in Carboxylation of Terminal Alkynes by MOF-Based Materials 3. CONVERSION OF CO2 INTO FUELS AND HYDROCARBONS 3.1. MOF-Based Materials as Photocatalysts for CO2 Conversion 3.2. Application of MOF in CO2 Conversion to Methanol 3.3. Conversion of CO2 into Formic Acid/ Formate 3.4. Conversion of CO2 to Methane CONCLUDING REMARKS LIST OF ABBREVIATIONS CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES Metal-Organic Framework Composites for Photocatalytic Water Purification Ning Yuan1,* and Xinling Zhang1 1. INTRODUCTION 2. SYNTHESIS OF MOF-BASED COMPOSITES 2.1. The Solvothermal Method 2.2. The Hydrothermal Method 2.3. The Ball-milling Method 2.4. The Ultrasonic-assisted Solvothermal Method 2.5. The Co-precipitation Method 3. PHOTOCATALYTIC WATER PURIFICATION Organic Pollutants 3.1. Dyes 3.2. Phenols 3.3. PPCPs 3.4. Herbicides and Pesticides 3.5. Other Organics 3.6. Inorganic Pollutants 3.7. Mixed Pollutants 3.8. The Correlation Between Photocatalytic Properties and Physical Properties of MOFs 4. ADSORPTION-PHOTOCATALYSIS SYNERGISTIC WATER PURIFICATION CONCLUSIONS AND PERSPECTIVES LIST OF ABBREVIATIONS CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES Subject Index Back Cover