The Iron(III) Thiocyanate Reaction: Research History and Role in Chemical Analysis
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This Brief presents an historical investigation into the reaction between ferric ions and thiocyanate ions, which has been viewed in different ways throughout the last two centuries. Historically, the reaction was used in chemical analysis and to highlight the nature of chemical reactions, the laws of chemistry, models and theories of chemistry, chemical nomenclature, mathematics and data analysis, and instrumentation, which are important ingredients of what one might call the nature of chemistry. Using the history of the iron(III) thiocyanate reaction as a basis, the book’s main objective is to explore how chemistry develops its own knowledge base; how it assesses the reliability of that base; and how some important tools of the trade have been brought to bear on a chemical reaction to achieve understanding, a worthwhile goal of any historical investigation. Front Matter ....Pages i-xi Introduction (Kevin C. de Berg)....Pages 1-18 The Reaction and Chemical Analysis (Kevin C. de Berg)....Pages 19-24 The Reaction and Its Nomenclature, Formulae, and Units (Kevin C. de Berg)....Pages 25-29 The Reaction: Chemical Affinity and Controversy (Kevin C. de Berg)....Pages 31-39 The Reaction: Chemical Affinity: Laws, Theories and Models (Kevin C. de Berg)....Pages 41-52 The Reaction and Its Equilibrium Constants: The Role of Mathematics and Data Analysis (Kevin C. de Berg)....Pages 53-69 The Reaction and Its Kinetics (Kevin C. de Berg)....Pages 71-86 The Reaction in Secondary and Tertiary Education Curricula (Kevin C. de Berg)....Pages 87-95 Conclusion (Kevin C. de Berg)....Pages 97-99
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