ENGLISH

State-to-State Dynamical Research in the F+H2 Reaction System

By Zefeng Ren (auth.)

Book information

Publisher
Springer-Verlag Berlin Heidelberg
Year
2014
ISBN
978-3-642-39755-4, 978-3-642-39756-1
DOI
10.1007/978-3-642-39756-1
Language
english
Format
PDF
Filesize
3 MB (3275544 bytes)
Series
Springer Theses
Edition
1
Pages
77\88
Time added
2013-12-12 02:00:00
Physical Chemistry;Atomic/Molecular Structure and

Description

This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.

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