Corrosion Protection of Metals and Alloys Using Graphene and Biopolymer Based Nanocomposites

Description

With contributions from experts from both academia and industry, this book provides up-to-date reviews and promising approaches for corrosion control of metals and alloys via sustainable biopolymers and carbon nanomaterials coatings, focusing on the wonder material “graphene” which is more solid than steel. This book delivers essential information for improving the environmental and economic viability of current coating technologies. It is also a valuable reference for those who are interested in corrosion science and corrosion protection including professionals from the industry as well as academia. Cover Corrosion Protection of Metals and Alloys Using Graphene and Biopolymer Based Nanocomposites Copyright Foreword Preface Acknowledgements Contents Section 1. Corrosion Protection by Natural/Biopolymer Coatings 1. Corrosion: Introduction 1. Introduction and History of Corrosion 2. Cost and Effect of Corrosion 3. Principle of Corrosion 4. Theory of Corrosion 5. Features of Corrosion 6. Types of Corrosion 6.1 General Corrosion 6.2 Intergranular Corrosion 6.3 Pitting Corrosion 6.4 Exfoliation 6.5 Dealloying or Selective Corrosion 6.6 Galvanic Corrosion 6.7 Water Line Attack 6.8 Filli-form Corrosion 6.9 Stress Corrosion Cracking 7. Thermodynamics of Corrosion 8. Kinetics of Corrosion 9. Corrosion Inhibition 9.1 Synthetic Inhibitors 9.2 Green Inhibitors 10. Concluding Remarks References 2. Biopolymer Composites and Nanocomposites for Corrosion Protection of Industrial Metal Substrates 1. Introduction 2. Biopolymer Composites and Nanocomposites for Corrosion Inhibition 2.1 Corrosion Inhibition by Chitosan Composites and Nanocomposites 2.2 Corrosion Inhibition by Carboxymethyl Cellulose Composites and Nanocomposites 2.3 Corrosion Inhibition by Other Biopolymer Composites and Nanocomposites 3. Mechanism of Inhibition by Biopolymer Composites and Nanocomposites 4. Conclusions References 3. Development of Green Vapor Phase Corrosion Inhibitors 1. Introduction 2. Volatile Components of Grape Pomace Extract 3. Effect of Grape Pomaces Extract and its Main Compounds on Corrosion Rate and Inhibition Efficiency 3.1 Gravimetric Measurements 3.2 Electrochemical Measurements 3.3 Scanning Electron Microscope (SEM) Surface Examination 3.4 Atomic Force Microscope (AFM) Surface Examination 3.5 FT-IR Analysis 4. Quantum Chemical Calculations 5. Explanation of Inhibition 6. Conclusions References 4. Plant-Based Green Corrosion Inhibition 1. Introduction 1.1 Properties of Green Inhibitors 1.2 Economical Worth of Green Inhibitors 1.3 Use of Plant Extracts as Corrosion Inhibitors 2. Categories of Major Plants as Green Corrosion Inhibitors 2.1 Guar Gum as a Corrosion Inhibitor 2.2 Azadirachta indica as a Corrosion Inhibitor 3. Nanocomposites as Green Inhibitors 4. Conclusions References 5. Corrosion Protection Using Organic and Natural Polymeric Inhibitors 1. Introduction: Corrosion Protection Methods 2. Adsorption Mechanisms of Inhibitors 3. Protection Performance Measurement Methods 4. Organic Inhibitors 5. Natural Inhibitors 6. Effects of Parameters of Inhibitor and Corrosive Medium on the Inhibition E 7. Corrosion Prevention on Metals Other than Steel 8. Conclusions References Section 2. Corrosion Protection Using Graphene and Other Smart Coatings 6. Carbon Nanoallotropes-Based Anticorrosive Coatings: Recent Advances and Future Perspectives 1. Introduction 2. Dimension-Based Classification of Carbon Allotropes as Anticorrosive Coatings 2.1 Zero-Dimensional: Carbon Dots- and Fullerene-Based Coatings 2.2 One-Dimensional: CNT-Based Coatings 2.3 Two-Dimensional: Graphene- and Graphene Oxide-Based Coatings 3. Concluding Remarks, Drawbacks and Future Perspectives 4. Acknowledgement References 7. Analytical Techniques for Corrosion-Related Characterization of Graphene and Graphene-Based Nanocomposites Coatings 1. Introduction 2. Imaging Examinations 2.1 SEM and TEM Imaging 2.2 AFM Imaging 3. Spectroscopic Examinations 3.1 EDS Examination 3.2 FTIR Spectroscopy 3.3 Raman Spectroscopy 3.4 X-ray Diffraction Examination 4. Thermal Stability Examination 5. Methods of Application of the Coatings and their Corrosion Examination 5.1 Corrosion Performance of Graphene Applied by Dip Coating 5.2 Corrosion Performance of Graphene Applied by Spray Coating 5.3 Corrosion Performance of Graphene Applied by Electrochemical Deposition 5.4 Corrosion Performance of Graphene Applied by CVD and LBL 5.5 Direct Application and Curing 5.6 Corrosion Performance of Graphene Applied by Spin Coating 5.7 Corrosion Performance of Graphene Nanocomposite Applied by Other Methods 6. Concluding Remarks 7. Acknowledgments References 8. Metal-Graphene Nanocomposites with Improved Mechanical and Anti-Corrosion Properties 1. General Aspects 2. Preparation Methods of Metal-Graphene Composites 2.1 Electrodeposition 2.2 Electrophoresis 2.3 Electroless Plating 2.4 Chemical Vapor Deposition 2.5 Other Methods 3. Properties of Metal-Graphene Composites 3.1 Morphology and Structure 3.2 Mechanical Properties 3.3 Corrosion Resistance 3.4 Others 4. Applications of Metal-Graphene Composites 4.1 Sensors and Biosensors 4.2 Energy Conversion 4.3 Biomedical Applications 5. Conclusions and Future Perspectives References 9. An Overview of the Effect of Graphene as a Metal Protector Against Microbiologically Influenced Corrosion (MIC) 1. Introduction: Microbiologically Influenced Corrosion (MIC) 2. Influence of MIC on Industry 3. Strategies for Prevention of MIC 4. Graphene: A Promising Corrosion Inhibitor Candidate 5. Recent Advances on the Application of Graphene as a Smart Anti-corrosive 6. Graphene as a Coating: Challenges and Approaches to Commercialization References 10. Advanced Micro/Nanocapsules for Self-healing Smart Anticorrosion Coatings 1. Introduction 2. Polymer-based Micro/Nano-Capsules 2.1 Developments in Polymeric Shell Materials 2.2 Shell Rupture and Healing Agent Sealing 2.3 Core Materials 2.4 Technological Applications 3. Inorganic Based Micro/Nano-capsules 3.1 Mesoporous Silica as Nanocontainers 3.2 Two Types of Nanocontainers in One Coating 3.3 Layered Double Hydroxides as Containers 3.4 Cation Exchange Clays 4. Polyelectrolyte Multilayer Based Micro/Nano-capsules 4.1 Polyelectrolyte Nanocontainers Composition and Production Methods 4.2 Breaking Mechanism for Polyelectrolyte Nanocontainers 4.3 Inhibitors Inside Polyelectrolyte Multilayer Nanocontainers 4.4 Applications for Polyelectrolyte Nanocontainer Self-healing Anti-corrosio 5. Concluding Remarks 6. Acknowledgments References 11. Plasma Electrolytic Oxidation Anticorrosive and Biocompatible Coatings 1. Introduction 2. Plasma Electrolytic Oxidation: An Overview 2.1 Advantages of PEO 2.2 Areas of Application 2.3 Set-up for PEO 2.4 Process Description 3. Wear-Resistant and Anticorrosive PEO 4. Biocompatible PEO Coatings 4.1 Bioactive PEO Coatings 4.2 Biodegradable PEO Coatings References Index