Inorganic Reactions and Methods: Electron-Transfer and Electrochemical Reactions; Photochemical and Other Energized Reactions, Volume 15

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How to Use this Book Preface to the Series Editorial Consultants to the Series Contributors to Volume 15 12. Electron-Transfer and Electrochemical Reactions 12.1. Introduction 12.2. Electron Transfer 12.3. Electrochemical Reactions 13. Photochemical and Other Energized Reactions 13.1. Introduction 13.2. Photosubstitution and Photoisomerization 13.3. Photoinduced Cleavage of Metal-Metal Bonds 13.4. Photoinduced Electron-Transfer Reactions 13.5. Pulse Radiolysis List of Abbreviations Author Index Compound Index Subject IndexContent: Chapter 12.2.1 Introduction (pages 1–5): J. J. Zuckerman, N. Sutin and R.G. LinckChapter 12.2.2.1 Outer?Sphere Reactions (pages 5–7): R.G. LinckChapter 12.2.2.1.2 Outer?Sphere Transition States (pages 7–9): R.G. LinckChapter 12.2.2.2 Inner?Sphere Reactions (pages 9–11): R.G. LinckChapter 12.2.2.2.2 Inner?Sphere Reactions: Scheme II (pages 11–12): R.G. LinckChapter 12.2.2.2.3 Inner?Sphere Reactions: Scheme III (pages 12–14): R.G. LinckChapter 12.2.2.2.4 Double?Ligand Bridging (page 14): R.G. LinckChapter 12.2.2.3 Other Reaction Classes (page 14): R.G. LinckChapter 12.2.2.3.2 Intramolecular Electron Transfer (pages 14–15): R.G. LinckChapter 12.2.2.3.3 Two?Electron Transfers (page 16): R.G. LinckChapter 12.2.3 Theory of Electron?Transfer Reactions (pages 16–17): N. SutinChapter 12.2.3.1 The Stability of the Precursor Complex (pages 17–19): N. SutinChapter 12.2.3.2 Potential?Energy Surfaces (page 20): N. SutinChapter 12.2.3.2.1 Of Zero Order (pages 20–22): N. SutinChapter 12.2.3.2.2 Of First Order (pages 22–23): N. SutinChapter 12.2.3.2.3 The Electronic Factor (pages 23–24): N. SutinChapter 12.2.3.3 Electron?Exchange Reactions (pages 24–26): N. SutinChapter 12.2.3.3.1 The Reorganization Energy (pages 26–29): N. SutinChapter 12.2.3.3.2 Nuclear Tunneling in Electron Exchange (pages 29–30): N. SutinChapter 12.2.3.3.3 Quantum?Mechanical Treatment (pages 30–31): N. SutinChapter 12.2.3.3.4 Comparison of Observed and Calculated Parameters for Electron Exchange (pages 32–37): N. SutinChapter 12.2.3.4 Electron Transfer Accompanied by a Net Chemical Change (pages 37–41): N. SutinChapter 12.2.3.4.2 Cross Reactions and Electron?Exchange Rates (pages 41–45): N. SutinChapter 12.2.3.4.3 Quantum?Mechanical Treatment (pages 45–46): N. SutinChapter 12.2.3.5 Conclusions (pages 46–49): C. Creutz and N. SutinChapter 12.2.4.1 The Inner?Shell Reorganization Energy: Exchange Rates of Aquo Ions (pages 49–53): C. Creutz and N. SutinChapter 12.2.4.2 Variations with Ligand: The Outer?Shell Reorganization Energy (pages 53–57): C. Creutz and N. SutinChapter 12.2.4.3 Electronic Factors: Nonadiabaticity (pages 58–59): C. Creutz and N. SutinChapter 12.2.4.4 Free?Energy Relations (pages 59–64): C. Creutz and N. SutinChapter 12.2.4.5 Inner?Sphere Versus Outer?Sphere Electron Transfer (pages 64–65): N. SutinChapter 12.2.4.6 Rate Saturation in Electron Transfer (pages 65–68): N. SutinChapter 12.2.5 Specific Reactivity Patterns in Electron?Transfer Reactions (pages 68–78): R.G. LinckChapter 12.2.5.1.2 Two?Electron Reductants (page 78): R.G. LinckChapter 12.2.5.2 Variation with the Oxidant (pages 78–81): R.G. LinckChapter 12.2.5.2.2 Multiple?Electron Oxidants (pages 81–82): R.G. LinckChapter 12.2.5.3 Oxidation and Reduction of Coordinated Ligands (page 82): R.G. LinckChapter 12.2.5.4 Catalysis in Electron?Transfer Reactions (pages 83–84): R.G. LinckChapter 12.2.5.4.2 Catalyzed Ligand Substitution (pages 84–85): R.G. LinckChapter 12.2.5.5 Induced Electron?Transfer Reactions (pages 85–86): R.G. LinckChapter 12.2.5.6 Photoinduced Electron?Transfer Reactions (pages 86–87): R.G. LinckChapter 12.3.1 Introduction (page 88): W.E. GeigerChapter 12.3.1.1 The Electrode Process (pages 88–90): W.E. GeigerChapter 12.3.1.2.2 Chemical Reversibility (pages 90–100): W.E. GeigerChapter 12.3.2.1.2 Pulse?Polarographic Methods (pages 100–106): W.E. GeigerChapter 12.3.2.1.3 Alternating?Current Polarography (pages 107–110): W.E. GeigerChapter 12.3.2.1.4 Cyclic Voltammetry (pages 110–116): W.E. GeigerChapter 12.3.3 Evaluation of Formal Potentials (pages 116–117): W.E. GeigerChapter 12.3.3.2 Involving Unstable Electrode Products (pages 118–123): W.E. GeigerChapter 12.3.3.3 Involving Reactants Undergoing Multiple?Electrode Reactions (pages 123–128): W.E. GeigerChapter 12.3.4 Chemical Reactions Accompanying Electrode Reactions (pages 128–129): W.E. GeigerChapter 12.3.4.1.2 Fast?Reaction (I ? A) Limit (pages 130–133): W.E. GeigerChapter 12.3.4.2 Reactions Following Electron Transfer (EC) (pages 133–135): W.E. GeigerChapter 12.3.4.2.2 Giving Electroactive Products (ECE) (pages 135–141): W.E. GeigerChapter 12.3.4.3 Other Coupled Chemical Reactions (pages 141–142): W.E. GeigerChapter 12.3.5 Electrochemical Synthesis (page 142): W.E. GeigerChapter 12.3.5.1 By Controlled?Potential Electrolysis (pages 142–145): W.E. GeigerChapter 12.3.5.2 Involving Bulk Preparations (pages 145–146): W.E. GeigerChapter 12.3.6 Thermodynamics of Simple Electrochemical Reactions (pages 147–150): M.J. WeaverChapter 12.3.7 Kinetics of Electrochemical Reactions (pages 150–153): M.J. WeaverChapter 12.3.7.2 Theory of Heterogeneous Electron?Transfer Reactions (pages 153–163): M.J. WeaverChapter 12.3.7.3 Double?Layer Effects in Electrochemical Kinetics (pages 164–165): M.J. WeaverChapter 12.3.7.4 Electrode?Reaction Mechanisms (pages 165–167): M.J. WeaverChapter 12.3.7.5 Influence of the Electrode Material (pages 168–171): M.J. WeaverChapter 12.3.7.6 Electrochemical Reactivity Patterns—Comparisons with Homogeneous Reactivities (pages 171–174): M.J. WeaverChapter 13.2 Photosubstitution and Photoisomerization (pages 175–179): G.L. Geoffroy and P.C. FordChapter 13.2.1 With Group VIA Complexes (pages 179–183): P.C. FordChapter 13.2.1.2 Of Molybdenum and Tungsten (pages 183–184): P.C. FordChapter 13.2.2 With Group VIIA Complexes (page 184): P.C. FordChapter 13.2.3 With Group VIII Complexes (pages 184–186): P.C. FordChapter 13.2.3.2 Of Ruthenium (pages 186–190): P.C. FordChapter 13.2.3.3 Of Osmium (page 190): P.C. FordChapter 13.2.3.4 Of Cobalt (pages 190–194): P.C. FordChapter 13.2.3.5 Of Rhodium(III) and Iridium(III) (pages 195–198): P.C. FordChapter 13.2.3.6 Of Nickel(II) and Palladium(II) (pages 198–199): P.C. FordChapter 13.2.3.7 Of Platinum(II) (pages 199–202): P.C. FordChapter 13.2.3.8 Of Platinum(IV) (pages 202–204): P.C. FordChapter 13.2.4 With Metal Carbonyls (pages 204–205): H.B. AbrahamsonChapter 13.2.4.1.1 Of Titanium, Zirconium and Hafnium (pages 205–206): H.B. AbrahamsonChapter 13.2.4.1.2 Of Vanadium, Niobium and Tantalum (pages 206–209): H.B. AbrahamsonChapter 13.2.4.1.3 Of Chromium, Molybdenum and Tungsten (pages 209–217): H.B. AbrahamsonChapter 13.2.4.1.4 Of Manganese and Rhenium (pages 217–221): H.B. AbrahamsonChapter 13.2.4.1.5 Of Iron, Ruthenium and Osmium (pages 221–224): H.B. AbrahamsonChapter 13.2.4.1.6 Of Cobalt, Rhodium and Iridium (pages 225–226): H.B. AbrahamsonChapter 13.2.4.1.7 Of Nickel (page 226): H.B. AbrahamsonChapter 13.2.4.2 Involving Dinuclear Complexes (pages 226–229): H.B. AbrahamsonChapter 13.2.4.3 Involving Polynuclear Complexes (pages 229–230): H.B. AbrahamsonChapter 13.2.5 With Other Organometallic Complexes (pages 230–235): G.L. GeoffroyChapter 13.2.5.2 Containing Isocyanides (pages 235–236): G.L. GeoffroyChapter 13.2.5.3 Containing Olefins (pages 236–240): G.L. GeoffroyChapter 13.2.5.4 Containing Arenes and Cyclopentadienyls (pages 240–242): G.L. GeoffroyChapter 13.2.5.5 Containing Alkyls (pages 242–245): G.L. GeoffroyChapter 13.3.1 In Dinuclear Complexes (pages 246–248): H.B. AbrahamsonChapter 13.3.1.1.2 And Contain Manganese, Technetium and Rhenium (pages 248–252): H.B. AbrahamsonChapter 13.3.1.1.3 And Contain Iron and Ruthenium (pages 252–254): H.B. AbrahamsonChapter 13.3.1.1.4 And Contain Cobalt (pages 254–255): H.B. AbrahamsonChapter 13.3.1.1.5 And Contain Nickel, Palladium and Platinum (pages 255–256): H.B. AbrahamsonChapter 13.3.1.2 That are Heteronuclear (pages 256–257): H.B. AbrahamsonChapter 13.3.2 In Polynuclear Complexes (pages 257–259): H.B. AbrahamsonChapter 13.4 Photoinduced Electron?Transfer Reactions (page 260): N. SutinChapter 13.4.1 Excited?State Assignments (pages 260–262): N. SutinChapter 13.4.2 Excited?State Electron Exchange (pages 262–265): N. SutinChapter 13.4.3 Quenching and Back Reactions (pages 265–268): N. SutinChapter 13.4.4 Free?Energy Relations (pages 269–271): N. SutinChapter 13.5.1 Introduction (pages 272–273): M.Z. HoffmanChapter 13.5.3 Techniques (pages 273–274): M.Z. HoffmanChapter 13.5.4.1 Of Hydrated Electrons (page 274): M.Z. HoffmanChapter 13.5.4.2 Of Hydroxyl Radicals (pages 274–275): M.Z. HoffmanChapter 13.5.4.3 Of Hydrogen Atoms (page 275): M.Z. HoffmanChapter 13.5.4.4 Of Secondary Radicals (pages 275–276): M.Z. HoffmanChapter 13.5.5 Of Metal Complexes (pages 276–277): M.Z. HoffmanChapter 13.5.5.1 Involving Groups IA and IIA (page 277): M.Z. HoffmanChapter 13.5.5.2 Involving Group IIIA (page 277): M.Z. HoffmanChapter 13.5.5.3 Involving Group IVA (page 277): M.Z. HoffmanChapter 13.5.5.4 Involving Group VA (pages 277–278): M.Z. HoffmanChapter 13.5.5.5 Involving Group VIA (pages 278–279): M.Z. HoffmanChapter 13.5.5.5.2 With Molybdenum and Tungsten (page 279): M.Z. HoffmanChapter 13.5.5.6 Involving Group VIIA (page 280): M.Z. HoffmanChapter 13.5.5.6.2 With Technetium (pages 280–281): M.Z. HoffmanChapter 13.5.5.7 Involving Group VIIIA (pages 281–282): M.Z. HoffmanChapter 13.5.5.7.2 With Ruthenium (pages 282–284): M.Z. HoffmanChapter 13.5.5.7.3 With Osmium (page 284): M.Z. HoffmanChapter 13.5.5.7.4 With Cobalt (pages 284–288): M.Z. HoffmanChapter 13.5.5.7.5 With Rhodium (pages 288–289): M.Z. HoffmanChapter 13.5.5.7.6 With Iridium (page 289): M.Z. HoffmanChapter 13.5.5.7.7 With Nickel (pages 289–290): M.Z. HoffmanChapter 13.5.5.7.8 With Palladium and Platinum (pages 290–291): M.Z. HoffmanChapter 13.5.5.8 Involving Group IB (pages 291–292): M.Z. HoffmanChapter 13.5.5.8.2 With Silver (pages 292–293): M.Z. HoffmanChapter 13.5.5.8.3 With Gold (page 293): M.Z. HoffmanChapter 13.5.5.9 Involving Group IIB (pages 293–294): M.Z. HoffmanChapter 13.5.5.9.2 With Cadmium (page 294): M.Z. HoffmanChapter 13.5.5.9.3 With Mercury (pages 294–295): M.Z. HoffmanChapter 13.5.5.10 Involving Group NIB (page 295): M.Z. HoffmanChapter 13.5.5.10.2 With Indium (page 295): M.Z. HoffmanChapter 13.5.5.10.3 With Thallium (page 295): M.Z. HoffmanChapter 13.5.5.11 Involving Group IVB (page 296): M.Z. HoffmanChapter 13.5.5.11.2 With Lead (page 296): M.Z. HoffmanChapter 13.5.5.12 Involving Lanthanides (page 296): M.Z. HoffmanChapter 13.5.5.13 Involving Actinides (page 297): M.Z. Hoffman