Organometallic Magnets

Description

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field. Front Matter ....Pages i-viii Hybrid Organic–Inorganic Cyanide-Bridged Networks (Tomasz Korzeniak, Beata Nowicka, Barbara Sieklucka)....Pages 1-34 Cobalt(II) Complexes as Single-Ion Magnets (Shalini Tripathi, Atanu Dey, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar)....Pages 35-75 Cobalt(II)/(III)–Lanthanide(III) Complexes as Molecular Magnets (Atanu Dey, Shalini Tripathi, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar)....Pages 77-100 Mannich Base Ligands as Versatile Platforms for SMMs (Enrique Colacio)....Pages 101-161 Tetrathiafulvalene-Based Magnets of Lanthanides (Olivier Cador, Fabrice Pointillart)....Pages 163-189 Geometry and Magnetism of Lanthanide Compounds (Zhenhua Zhu, Jinkui Tang)....Pages 191-226 Single-Ion Anisotropy: An Insight to Complicated Magnetic Molecules (Shang-Da Jiang, Bing-Wu Wang, Song Gao)....Pages 227-252 Lanthanide Organometallics as Single-Molecule Magnets (María José Heras Ojea, Lewis C. H. Maddock, Richard A. Layfield)....Pages 253-280 Role of Ab Initio Calculations in the Design and Development of Lanthanide Based Single Molecule Magnets (Tulika Gupta, Mukesh Kumar Singh, Gopalan Rajaraman)....Pages 281-354 Complete Active Space Wavefunction-Based Analysis of Magnetization and Electronic Structure (Frédéric Gendron, Hélène Bolvin, Jochen Autschbach)....Pages 355-390 Magnetism of Actinide Coordination Compounds (Jan van Leusen, Manfred Speldrich, Paul Kögerler)....Pages 391-410 Correction to: Cobalt(II) Complexes as Single-Ion Magnets (Shalini Tripathi, Atanu Dey, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar)....Pages 411-411 Correction to: Cobalt(II)/(III)–Lanthanide(III) Complexes as Molecular Magnets (Atanu Dey, Shalini Tripathi, Maheswaran Shanmugam, Ramakirushnan Suriya Narayanan, Vadapalli Chandrasekhar)....Pages 413-413 Back Matter ....Pages 415-418