Polyoxometalate-Based Assemblies and Functional Materials
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Description
The authors of this volume concentrate on the recent progress of novel polyoxometalate (POM) syntheses, as well as advances made in catalytic, electrochemical, and sensing systems. The state-of-the-art techniques such as flow system and gel-electrophoresis for the discovery of POMs are covered with a detailed discussion. Of particular importance, the application of POM-based materials in photo-sensing, heterogeneous catalysis, energy conservation and storage, and gas separation is reviewed. Over the past few years, POM chemistry has witnessed a remarkable progress with more than 1500 papers published each year. Due to their intrinsic structural features, POMs are considered as versatile building blocks for the construction of sophisticated complex assemblies and advanced multi-functional materials. Various strategies, methods, and techniques have been adopted to develop POM-based materials with intriguing properties and excellent performance. All the contributors to this volume are young, vibrant chemists in this research field and all the works are carefully collected from the authors’ years of experience. This volume serves as an essential reference for every POM chemist and is of great interest to new researchers who wish to learn more about this area. Front Matter ....Pages i-vii Building Block Libraries and Structural Considerations in the Self-assembly of Polyoxometalate and Polyoxothiometalate Systems (James McAllister, Haralampos N. Miras)....Pages 1-29 Structure and Bonding in Molecular Vanadium Oxides: From Templates via Host–Guest Chemistry to Applications (Carsten Streb)....Pages 31-47 Polyoxometalate-Based Photo-Sensitive Functional Hybrid Materials (Chang-Gen Lin, Wei Chen, Yu-Fei Song)....Pages 49-63 Porous Ionic Crystals Based on Polyoxometalates (Sayaka Uchida)....Pages 65-87 Polyoxometalates Assemblies and Their Electrochemical Applications (Wenjing Liu, Xiao-Li Wang, Ya-Qian Lan)....Pages 89-119 Gel-Electrophoretic Chromatography of Polyoxometalate Clusters in Aqueous Solution (Ryo Tsunashima)....Pages 121-137 Alkoxido-Derivatised Lindqvist- and Keggin-Type Polyoxometalates (R. John Errington, Balamurugan Kandasamy, Daniel Lebbie, Thompson Izuagie)....Pages 139-163 Back Matter ....Pages 165-167
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