Inorganic Chemistry

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Cover Inorganic Chemistry Copyright Contents Preface to the Second Edition Preface to the First Edition Part 1 - Structure of Atoms and Molecules Chapter 1 - Light, Electrons, and Nuclei 1.1 SOME EARLY EXPERIMENTS IN ATOMIC PHYSICS 1.2 THE NATURE OF LIGHT 1.3 THE BOHR MODEL 1.4 PARTICLEeWAVE DUALITY 1.6 NUCLEAR BINDING ENERGY 1.7 NUCLEAR STABILITY 1.8 TYPES OF NUCLEAR DECAY References for Further Study QUESTIONS AND PROBLEMS Chapter 2 - Basic Quantum Mechanics and Atomic Structure 2.1 THE POSTULATES 2.2 THE HYDROGEN ATOM 2.3 THE HELIUM ATOM 2.4 SLATER WAVE FUNCTIONS 2.5 ELECTRON CONFIGURATIONS 2.6 SPECTROSCOPIC STATES References for Further Study QUESTIONS AND PROBLEMS 3 - Covalent Bonding in Diatomic Molecules 3.1 THE BASIC IDEAS OF MOLECULAR ORBITAL METHODS 3.2 THE H+2 AND H2 MOLECULES 3.3 DIATOMIC MOLECULES OF SECOND-ROW ELEMENTS 3.4 PHOTOELECTRON SPECTROSCOPY 3.5 HETERONUCLEAR DIATOMIC MOLECULES 3.6 ELECTRONEGATIVITY 3.7 SPECTROSCOPIC STATES FOR MOLECULES References for Further Study QUESTIONS AND PROBLEMS Chapter 4 - A Survey of Inorganic Structures and Bonding 4.1 STRUCTURES OF MOLECULES HAVING SINGLE BONDS 4.2 RESONANCE AND FORMAL CHARGE 4.3 COMPLEX STRUCTURES: A PREVIEW OF COMING ATTRACTIONS 4.4 ELECTRON-DEFICIENT MOLECULES 4.5 STRUCTURES HAVING UNSATURATED RINGS 4.6 BOND ENERGIES References for Further Study QUESTIONS AND PROBLEMS Chapter 5 - Symmetry and Molecular Orbitals 5.1 SYMMETRY ELEMENTS 5.2 ORBITAL SYMMETRY 5.3 A BRIEF LOOK AT GROUP THEORY 5.4 CONSTRUCTION OF MOLECULAR ORBITALS 5.5 ORBITALS AND ANGLES 5.6 SIMPLE CALCULATIONS USING THE HÜCKEL METHOD References for Further Study QUESTIONS AND PROBLEMS Part 2 - Condensed Phases Chapter 6 - Dipole Moments and Intermolecular Interactions 6.1 DIPOLE MOMENTS 6.2 DIPOLE-DIPOLE FORCES 6.3 DIPOLE-INDUCED DIPOLE FORCES 6.4 LONDON (DISPERSION) FORCES 6.5 THE VAN DER WAALS EQUATION 6.6 HYDROGEN BONDING 6.7 COHESION ENERGY AND SOLUBILITY PARAMETERS 6.8 SOLVATOCHROMISM References for Further Study QUESTIONS AND PROBLEMS Chapter 7 - Ionic Bonding and Structures of Solids 7.1 ENERGETICS OF CRYSTAL FORMATION 7.2 MADELUNG CONSTANTS 7.3 THE KAPUSTINSKII EQUATION 7.4 IONIC SIZES AND CRYSTAL ENVIRONMENTS 7.5 CRYSTAL STRUCTURES 7.6 SOLUBILITY OF IONIC COMPOUNDS 7.7 PROTON AND ELECTRON AFFINITIES 7.8 STRUCTURES OF METALS 7.9 DEFECTS IN CRYSTALS 7.10 PHASE TRANSITIONS IN SOLIDS 7.11 HEAT CAPACITY 7.12 HARDNESS OF SOLIDS References for Further Study QUESTIONS AND PROBLEMS Chapter 8 - Dynamic Processes in Inorganic Solids 8.1 CHARACTERISTICS OF SOLID-STATE REACTIONS 8.2 KINETIC MODELS FOR REACTIONS IN SOLIDS 8.3 THERMAL METHODS OF ANALYSIS 8.4 EFFECTS OF PRESSURE 8.5 REACTIONS IN SOME SOLID INORGANIC COMPOUNDS 8.6 PHASE TRANSITIONS 8.7 REACTIONS AT INTERFACES 8.8 DIFFUSION IN SOLIDS 8.9 SINTERING 8.10 DRIFT AND CONDUCTIVITY References for Further Study QUESTIONS AND PROBLEMS Part 3 - Acids, Bases, and Solvents Chapter 9 - Acid–Base Chemistry 9.1 ARRHENIUS THEORY 9.2 BRØNSTE–LOWRY THEORY 9.3 FACTORS AFFECTING THE STRENGTH OF ACIDS AND BASES 9.4 ACID–BASE CHARACTER OF OXIDES 9.5 PROTON AFFINITIES 9.6 LEWIS THEORY 9.7 CATALYTIC BEHAVIOR OF ACIDS AND BASES 9.8 THE HARD–SOFT INTERACTION PRINCIPLE (HSIP) 9.9 ELECTRONIC POLARIZABILITIES 9.10 THE DRAGO FOUR-PARAMETER EQUATION References for Further Study QUESTIONS AND PROBLEMS Chapter 10 - Chemistry in Nonaqueous Solvents 10.1 SOME COMMON NONAQUEOUS SOLVENTS 10.2 THE SOLVENT CONCEPT 10.3 AMPHOTERIC BEHAVIOR 10.4 THE COORDINATION MODEL 10.5 CHEMISTRY IN LIQUID AMMONIA 10.6 LIQUID HYDROGEN FLUORIDE 10.7 LIQUID SULFUR DIOXIDE 10.8 SUPERACIDS References for Further Reading QUESTIONS AND PROBLEMS Part 4 - Chemistry of the Elements Chapter 11 - Chemistry of Metallic Elements 11.1 THE METALLIC ELEMENTS 11.2 BAND THEORY 11.3 GROUPS IA AND IIA METALS 11.4 ZINTL PHASES 11.5 ALUMINUM AND BERYLLIUM 11.6 THE FIRST-ROW TRANSITION METALS 11.7 SECOND- AND THIRD-ROW TRANSITION METALS 11.8 ALLOYS 11.9 CHEMISTRY OF TRANSITION METALS 11.10 THE LANTHANIDES References for Further Reading QUESTIONS AND PROBLEMS Chapter 12 - Organometallic Compounds of the Main Group Elements 12.1 PREPARATION OF ORGANOMETALLIC COMPOUNDS 12.2 ORGANOMETALLIC COMPOUNDS OF GROUP IA METALS 12.3 ORGANOMETALLIC COMPOUNDS OF GROUP IIA METALS 12.4 ORGANOMETALLIC COMPOUNDS OF GROUP IIIA METALS 12.5 ORGANOMETALLIC COMPOUNDS OF GROUP IVA METALS 12.6 ORGANOMETALLIC COMPOUNDS OF GROUP VA ELEMENTS 12.7 ORGANOMETALLIC COMPOUNDS OF Zn, Cd, AND Hg References for Further Study QUESTIONS AND PROBLEMS Chapter 13 - Chemistry of Nonmetallic Elements I. Hydrogen, Boron, Oxygen, and Carbon 13.1 HYDROGEN 13.2 BORON 13.3 OXYGEN 13.4 CARBON References for Further Reading QUESTIONS AND PROBLEMS Chapter 14 - Chemistry of Nonmetallic Elements II. Groups IVA and VA 14.1 THE GROUP IVA ELEMENTS 14.2 NITROGEN 14.3 PHOSPHORUS, ARSENIC, ANTIMONY, AND BISMUTH References for Further Reading QUESTIONS AND PROBLEMS Chapter 15 - Chemistry of Nonmetallic Elements III. Groups VIA–VIIIA 15.1 SULFUR, SELENIUM, AND TELLURIUM 15.2 THE HALOGENS 15.3 THE NOBLE GASES References for Further Reading QUESTIONS AND PROBLEMS Part 5 - Chemistry of Coordination Compounds Chapter 16 - Introduction to Coordination Chemistry 16.1 STRUCTURES OF COORDINATION COMPOUNDS 16.2 METAL–LIGAND BONDS 16.3 NAMING COORDINATION COMPOUNDS 16.4 ISOMERISM 16.5 A SIMPLE VALENCE BOND DESCRIPTIONOF COORDINATE BONDS 16.6 MAGNETISM 16.7 A SURVEY OF COMPLEXES OF FIRST-ROW METALS 16.8 COMPLEXES OF SECOND- AND THIRD-ROW METALS 16.9 THE 18-ELECTRON RULE 16.10 BACK DONATION 16.11 COMPLEXES OF DINITROGEN, DIOXYGEN, AND DIHYDROGEN References for Further Study QUESTIONS AND PROBLEMS Chapter 17 - Ligand Fields and Molecular Orbitals 17.1 SPLITTING OF d ORBITAL ENERGIES IN OCTAHEDRAL FIELDS 17.2 SPLITTING OF d ORBITAL ENERGIES IN FIELDS OF OTHERSYMMETRY 17.3 FACTORS AFFECTING ? 17.4 CONSEQUENCES OF CRYSTAL FIELD SPLITTING 17.5 JAHN–TELLER DISTORTION 17.6 SPECTRAL BANDS 17.7 MOLECULAR ORBITALS IN COMPLEXES References for Further Study QUESTIONS AND PROBLEMS Chapter 18 - Interpretation of Spectra 18.1 SPLITTING OF SPECTROSCOPIC STATES 18.2 ORGEL DIAGRAMS 18.3 RACAH PARAMETERS AND QUANTITATIVE METHODS 18.4 THE NEPHELAUXETIC EFFECT 18.5 TANABE–SUGANO DIAGRAMS 18.6 THE LEVER METHOD 18.7 JØRGENSEN’S METHOD 18.8 CHARGE TRANSFER ABSORPTION 18.9 SOLVATOCHROMISM 18.9 SOLVATOCHROMISM References for Further Study QUESTIONS AND PROBLEMS Chapter 19 - Composition and Stability of Complexes 19.1 COMPOSITION OF COMPLEXES IN SOLUTION 19.2 JOB’S METHOD OF CONTINUOUS VARIATIONS 19.3 EQUILIBRIA INVOLVING COMPLEXES 19.4 DISTRIBUTION DIAGRAMS 19.5 FACTORS AFFECTING THE STABILITY OF COMPLEXES References for Further Study QUESTIONS AND PROBLEMS Chapter 20 - Synthesis and Reactions of Coordination Compounds 20.1 SYNTHESIS OF COORDINATION COMPOUNDS 20.2 SUBSTITUTION REACTIONS IN OCTAHEDRAL COMPLEXES 20.3 LIGAND FIELD EFFECTS 20.4 ACID-CATALYZED REACTIONS OF COMPLEXES 20.5 BASE-CATALYZED REACTIONS OF COMPLEXES 20.6 THE COMPENSATION EFFECT 20.7 LINKAGE ISOMERIZATION 20.8 SUBSTITUTION IN SQUARE PLANAR COMPLEXES 20.9 THE TRANS EFFECT 20.10 ELECTRON TRANSFER REACTIONS 20.11 REACTIONS IN SOLID COORDINATION COMPOUNDS References for Further Study QUESTIONS AND PROBLEMS Chapter 21 - Complexes Containing Metal–Carbon and Metal–Metal Bonds 21.1 BINARY METAL CARBONYLS 21.2 STRUCTURES OF METAL CARBONYLS 21.3 BONDING OF CARBON MONOXIDE TO METALS 21.4 PREPARATION OF METAL CARBONYLS 21.5 REACTIONS OF METAL CARBONYLS 21.6 STRUCTURE AND BONDING IN METAL–ALKENE COMPLEXES 21.7 PREPARATION OF METAL–ALKENE COMPLEXES 21.8 CHEMISTRY OF CYCLOPENTADIENYL AND RELATEDCOMPLEXES 21.9 BONDING IN FERROCENE 21.10 REACTIONS OF FERROCENE AND OTHER METALLOCENES 21.11 COMPLEXES OF BENZENE AND RELATED AROMATICS 21.12 COMPOUNDS CONTAINING METAL–METAL BONDS References for Further Study QUESTIONS AND PROBLEMS Chapter 22 - Coordination Compounds in Catalysis 22.1 ELEMENTARY STEPS IN CATALYTIC PROCESSES 22.2 HOMOGENEOUS CATALYSIS References for Further Study QUESTIONS AND PROBLEMS Chapter 23 - Bioinorganic Chemistry 23.1 WHAT METALS DO IN SOME LIVING SYSTEMS 23.2 CYTOTOXICITY OF SOME METAL COMPOUNDS 23.3 ANTIMALARIAL METALLODRUGS References for Further Study QUESTIONS AND PROBLEMS Appendix A - Ionization Energies Appendix B - Character Tables for Selected Point Groups Index